(2,3,9,10,16,17,23,24-octamethoxyphthalocyaninato)titanium(III) chloride | 1233237-18-7

• 英文名称: (2,3,9,10,16,17,23,24-octamethoxyphthalocyaninato)titanium(III) chloride
• 英文别名: [(MeO)8PcTiCl]
• CAS: 1233237-18-7
• 化学式: C₄₀H₃₂ClN₈O₈Ti
• 分子量: 836.076
• InChiKey: NVBLPWKQEMERRA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,5-二甲氧基苯二氰 在 titanium(III) chloride 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 无水二甲氨基乙醇 为溶剂， 反应 0.17h， 以40%的产率得到(2,3,9,10,16,17,23,24-octamethoxyphthalocyaninato)titanium(III) chloride
  参考文献：
  名称：

  Efficient green procedures for the preparation of novel tetraalkynyl-substituted phthalocyanines

  摘要：

  This work provides a successful, easy and efficient process for the preparation of metal-free 2(3),9(10),16(17),23(24)-octamethoxyphthalocyanine, [(OMe)(8)PcH2] (2), and its metal complexes [(OMe)(8)PcM] (3-11) (M = Zn, Cu, Ni, Mg, Co, Fe, Ru, TiCl and RhCl) by using green energy techniques such as exposure to UV-irradiation as well as microwave irradiation. Two different routes have been used, which involve modifications to that reported in the literature. The results suggest that these techniques drastically reduce the reaction time of metallophthalocyanine [(OMe)(8)PcM] (3-11) formation from 5-96 h to 5-11 min. The prepared octamethoxyphthalocyanines [OMe)(8)PcM] (2-4) (M Zn, Cu) are used as key materials to synthesize the corresponding novel tetraalkynyl-substituted phthalocyanines 15-17. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.02.034