| 180402-02-2

• CAS: 180402-02-2
• 化学式: C₁₂H₄F₂₀O₂P₂Pt
• 分子量: 817.158
• InChiKey: SRNAAVUVASLRLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 not given 为溶剂， 生成
  参考文献：
  名称：

  Bennett, Byron L.; Roddick, Dean M., Inorganic Chemistry, 1996, vol. 35, # 16, p. 4703 - 4707

  摘要：

  DOI：
• 作为产物：
  描述：

  以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Bennett, Byron L.; Roddick, Dean M., Inorganic Chemistry, 1996, vol. 35, # 16, p. 4703 - 4707

  摘要：

  DOI：

文献信息

• Thermal elimination reactions of (dfepe)Pt(CF3)X (fluoroalkyl)phosphine complexes (X = Cl, O2CCF3): synthesis and structural characterization of an unusual chelate-bridged platinum(0) complex, [(dfepe)Pt(CO)]2(μ-dfepe)
  作者：R.Gregory Peters、Byron L. Bennett、Dean M. Roddick

  DOI：10.1016/s0020-1693(97)05692-2

  日期：1997.11

  Platinum trifluoromethyl-substituted (fluoroalkyl) phosphine complexes (dfepe)Pt(CF3) (X) (dfepe = (C2F5)(2)PCH2CH2P(C2F5)(2), X = Cl, O2CCF3) have been prepared from the corresponding cyclooctadiene precursors, (cod)Pt(CF3) (X), and have been fully characterized by F-19 and P-31 NMR spectroscopy. Thermolyses of (dfepe)Pt(CF3) X complexes in acetone at 100 degrees lead to elimination and disproportionation to give (dfepe)(2)Pt and unidentified Pt(O) products. In the presence of carbon monoxide, an initial dfepe loss prior to Pt-CF3 elimination is observed and subsequent trapping by dfepe and CO produces (dfepe)Pt(CO)(2). In the presence of additional dfepe, (dfepe)Pt(CO)(2) reacts further after cooling to ultimately afford a new platinum(O) carbonyl dfepe-bridged dimer, [(dfepe)Pt(CO)](2)(mu-dfepe). Crystallographic data for this molecule reveals an unusual distorted-tetrahedral platinum coordination environment and a dfepe-bridged geometry. Crystal data for [(dfepe)Pt(CO)](2)(mu-dfepe): triclinic, P (1) over bar (No. 2), a = 8.802(2), b = 10.581(2), c = 16.506(3) Angstrom, alpha = 74.75(3), beta = 78.03(3),gamma = 78.30(3)degrees, V = 1432.9(5) Angstrom(3), Z = 1, R = 0.0337, wR(2) = 0.0858. (C) 1997 Elsevier Science S.A.