[RuCl(η6-p-cymene)(η1-NH=C(H)-p-tolyl)PPh2(OEt)]BPh4] | 1219623-08-1

• 英文名称: [RuCl(η6-p-cymene)(η1-NH=C(H)-p-tolyl)PPh2(OEt)]BPh4]
• CAS: 1219623-08-1
• 化学式: C₂₄H₂₀B*C₃₂H₃₈ClNOPRu
• 分子量: 939.39
• InChiKey: SFAZYXHROXGRLM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuCl2(η6-p-cymene)PPh2(OEt)] 、 1-(迭氮基甲基)-4-甲苯 、 四苯硼钠 以 乙醇 为溶剂， 以68%的产率得到[RuCl(η6-p-cymene)(η1-NH=C(H)-p-tolyl)PPh2(OEt)]BPh4]
  参考文献：
  名称：

  Preparation of imine complexes of ruthenium and osmium stabilised by [MCl(η 6-p-cymene)(PR3)]+ fragments

  摘要：

  Imine complexes [MCl(eta (6)-p-cymene){eta(1)-NH=C(H)Ar}(PR3)]BPh4 (1-3) [M = Ru, Os; PR3 = PPh(OEt)(2), PPh2OEt; Ar = Ph, p-tolyl] were prepared by reacting MCl2(eta (6)-p-cymene)(PR3) precursors with benzyl azide ArCH2N3 in the presence of NaBPh4. Benzophenone-imine complexes [MCl(eta (6)-p-cymene){eta(1)-NH=CPh2}(PR3)]BPh4 (4-6) [M = Ru, Os; PR3 = PPh(OEt)(2), PPh2OEt] were also prepared by allowing MCl2(eta 6-p-cymene)(PR3) to react with Ph2C=NH in the presence of NaBPh4. The complexes were characterised spectroscopically (IR, H-1, C-13, P-31, N-15 NMR) and by X-ray crystal structure determination of [RuCl(eta (6)-p-cymene){eta(1)-NH=C(H)-p-tolyl}{PPh(OEt)(2)}]BPh4 (1b). (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.11.008