((t-Bu2PCH2SiMe2)2N)Rh[η2-H2C=CH(OEt)] | 1006607-80-2

• 英文名称: ((t-Bu2PCH2SiMe2)2N)Rh[η2-H2C=CH(OEt)]
• CAS: 1006607-80-2
• 化学式: C₂₆H₆₀NOP₂RhSi₂
• 分子量: 623.793
• InChiKey: XLPAXIPVOUPGSR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ((tBu2PCH2SiMe2)2CH2CMe2N)RhH 、 乙烯基乙醚 以 苯 为溶剂， 生成 ((t-Bu2PCH2SiMe2)2N)Rh[η2-H2C=CH(OEt)]
  参考文献：
  名称：

  [(^tBu₂PCH₂SiMe₂)₂N]Rh^I? Rapidly Reversible H−C(sp³) and H−C(sp²) Bond Cleavage by Rhodium(I)

  摘要：

  The product of the reaction of ((Bu2PCH2SiMe2)-Bu-t)(2)N- (MgCl+ salt) with [RhCl(cyclooctene)(2)](2) is a Rh-III complex where one Bu-t methyl C-H bond has oxidatively added to Rh: (PNP*)RhH. This is in rapid exchange among all 9 x 4 C-H bonds of the four Bu-t groups. (PNP*)RhH undergoes oxidative addition equilibrium with the C-H bonds of benzene at similar to 10(3) S-I at 25 degrees C and oxidatively adds the ring C-H of other arenes. (PNP*)RhH forms eta(2)-olefin complexes with several olefins and dehydrogenates allylic C-H bonds to form (PNP)Rh(H)(2).

  DOI：

  10.1021/om701165n