| 482315-32-2

• CAS: 482315-32-2
• 化学式: C₂₆H₂₇N₃O₃Ru
• 分子量: 530.589
• InChiKey: AUTTYMXPMRLXNQ-HESHWDSWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [ruthenium(II)(hydride)(chloride)(carbonyl)(pyridyl)(triphenylphosphine)2] 、 o-hydroxy acetophenone tetramethylenediimine 以 苯 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  SYNTHESIS AND BIOLOGICAL ACTIVITY OF RUTHENIUM(II) CARBONYL COMPLEXES CONTAINING TETRADENTATE SCHIFF BASES

  摘要：

  Several hexa-coordinated ruthenium(II) carbonyl complexes of the type [Ru(CO)(B)(L)] (B = PPh3, pyridine (py), piperidine (pip) or morpholine (morph); H2L = tetradentate Schiff bases) have been prepared by the reactions of [RuHCl(CO)(PPh3)2(B)] (B = PPh3 or py or pip or morph) with appropriate Schiff bases having the donor groups O,N viz., o-hydroxyacetophenoneethylenediimine, H-2(o-hyacen); o-hydroxyacetophenonepropylenediimine, H-2(o-hyacpn); o-hydroxyacetophenonetetramethylenediimine, H-2(o-hyactn), and o-hydroxyacetophenone-ortho-phenylenediimine, H-2(o-hyacopn), in 1:1 molar ratio. The complexes have been characterised on the basis of elemental analyses and spectral (IR, electronic, H-1 and P-31 NMR) data. The antibacterial activities of these new complexes were also tested.

  DOI：

  10.1081/sim-120014309

文献信息

• Synthesis, characterization and catalytic activities of ruthenium complexes containing triphenylphosphine/triphenylarsine and tetradentate Schiff bases
  作者：R Karvembu、S Hemalatha、R Prabhakaran、K Natarajan

  DOI：10.1016/s1387-7003(03)00021-2

  日期：2003.5

  Abstract Ruthenium(II) complexes of the type [Ru(CO)(B)(L)] (B=AsPh3, pyridine, piperidine or morpholine; L=dianion of tetradentate Schiff bases) have been synthesized and characterized by physico-chemical methods. These complexes are found to be effective catalysts in the oxidation of primary and secondary alcohols using N-methylmorpholine-N-oxide as oxidant. The catalytic activity of these triphenylarsine

  摘要 [Ru(CO)(B)(L)] 型钌 (II) 配合物（B=AsPh3、吡啶、哌啶或吗啉；L=四齿席夫碱的二价阴离子）已被合成并通过物理化学方法表征. 发现这些配合物是使用 N-甲基吗啉-N-氧化物作为氧化剂氧化伯醇和仲醇的有效催化剂。这些三苯胂配合物的催化活性已与三苯膦配合物和类似的钌 (III) 配合物进行了比较。建议在催化过程中形成高价 Run+2O 物种作为催化中间体。