[(indenyl)MoH(η5-C5H5)((P(OMe)3)]PF6 | 933782-76-4

• 英文名称: [(indenyl)MoH(η5-C5H5)((P(OMe)3)]PF6
• CAS: 933782-76-4
• 化学式: C₁₇H₂₂MoO₃P*F₆P
• 分子量: 546.238
• InChiKey: JPYNLURVMQNSIG-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  sodium tetrahydroborate 、 [(indenyl)Mo(η5-C5H5)((P(OMe)3)2](PF6)2 以 丙酮 为溶剂， 以91%的产率得到[(indenyl)MoH(η5-C5H5)((P(OMe)3)]PF6
  参考文献：
  名称：

  Synthesis and structural characterization of new mixed-ring indenyl derivatives of molybdenum containing phosphorus ligands

  摘要：

  Reaction of NaBH4 with [IndCpMo(dppe)](BF4)(2) (1) in acetone yields [IndMo(eta(4)-C5H6)(dppe)]BF4 (2) quantitatively. The hydride addition takes place at the external face of the Cp ring. Dissolution of 2 in dichloromethane gives [IndMo(eta(4)-C5H5-exo-CH2Cl)(dppe)]BF4, as confirmed by elemental analysis, IR and H-1 NMR spectroscopy. The similar dication [IndCpMo- {P(OMe)(3))(2)](BF4)(2) (4) reacts with NaBH4, in a solvent dependent manner. In acetonitrile, [IndMo(eta(4)-C5H6){P(OMe)(3)}(2)]BF4 (5) is obtained and in acetone a P(OMe)(3) ligand is lost resulting in the asymmetric phosphite-hydride, [IndCpMoH{P(OMe)(3)}](+) (6). The molecular structures of [IndMo(eta(4)-C5H6){P(OMe)(3)}(2)]PF6 and [IndCpMoH{P(OMe)(3)}]PF6 were characterized by single-crystal X-ray diffraction. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.12.015