| 176730-85-1

• CAS: 176730-85-1
• 化学式: C₃₀H₃₂AuP₂S₂*F₆P
• 分子量: 860.594
• InChiKey: WYUYQBILBIDGOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  thallium(I) hexafluorophosphate 、 (tetrahydrothiophene)gold(I) chloride 、 1.2-Bis--aethan 以 乙腈 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Synthesis and characterisation of mono- and di-nuclear mixed phosphathia complexes of gold(I): crystal structures of [Au(RSC₂H₄SR)]PF₆, [Au(RSC₃H₆SR)]PF₆and [Au₂(RSC₂H₄SR)₂]Cl₂·4CH₂Cl₂(R = Ph₂PC₂H₄)

  摘要：

  Mononuclear gold(I) complexes of two linear P2S2 donor ligands, [AuL]PF6 [L = RSC(2)H(4)SR or RSC(3)H(6)SR (R = Ph(2)PC(2)H(4))] have been prepared by reaction of [AuCl(tht)] (tht = tetrahydrothiophene) with L and TIPF6 in MeCN solution. The crystal structure of [Au(RSC(2)H(4)SR)](+) shows a primary P-2-donor set with additional long-range thioether interactions giving a distorted linear geometry around Au-1 in the solid state; Au-P 2.284(7), 2.302(7), Au ... S 2.899(6), 3.190(7) Angstrom. The structure of [Au(RSC(3)H(6)SR)](+) shows a very similar arrangement; Au-P 2.279(6), 2.287(6) Angstrom, Au ... S 3.097(5), 3.101(6) Angstrom. The non-conducting binuclear species [Au(2)Cl(2)L] were obtained by reaction of [AuCl(tht)] with L in a 2: 1 molar ratio in CH2Cl2 solution, while a 1.1 [AuCl(tht)]: RSC(2)H(4)SR ratio yielded the unusual species [Au-2(RSC(2)H(4)SR)(2)]Cl-2, the crystal structure of which shows a linear P-2-donor set at each Au, giving a helical cavity which contains a Cl- anion. All complexes have been characterised by IR, H-1 and P-31 NMR spectroscopies, FAB mass spectrometry and microanalyses.

  DOI：

  10.1039/dt9960001267