[Pt(NH2CH2CH2NCl)(pyridine)Cl3] | 1205532-65-5

• 英文名称: [Pt(NH2CH2CH2NCl)(pyridine)Cl3]
• CAS: 1205532-65-5；19385-40-1
• 化学式: C₇H₁₁Cl₄N₃Pt
• 分子量: 474.076
• InChiKey: GJDZBKHGGFUPQP-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  {PtenCl4}*2C5H5N 、 氯 以 水 、 乙腈 为溶剂， 生成 [Pt(NH2CH2CH2NCl)(pyridine)Cl3]
  参考文献：
  名称：

  Chlorine oxidation of coordinated ethylenediamine in triamineplatinum(IV) complex [PtEnPyCl3]Cl. Molecular structure of [PtPy(NH2-CH2-C≡N)Cl4] and [PtPy(NCl-(CH2)2-NH2)Cl3] crystals

  摘要：

  The reaction of chlorine with triamine [PtEnPyCl(3)]Cl in aqueous solution yields an insoluble powdered product, which is a mixture of compounds. Extraction with acetonitrile isolates a number of complexes: a glassy polymeric product (I), which contains a C=O group, an amino group, and pyridine; [PtPy(NH2CH2CN)Cl-4] (II) as the major product (ethylenediamine converts to aminoacetonitrile as a result of oxidative dehydrogenation); and the aminochloro complex [PtPy(NClCH2CH2NH2)Cl-3] (III) in a minor amount. The IR spectra of the products were studied. X-ray structure analysis was carried out for complexes II and III. Compound II: orthorhombic space group Pbcm, a = 10.925(2) angstrom, b = 11.413(2) angstrom, c = 9.979(2) angstrom, V = 1244.3(4) angstrom(3), Z = 8, R-hk1 = 0.033. The aminoacetonitrile molecule is coordinated to the platinum atom via the amino nitrogen atom in the trans position to pyridine; C N 1.07(2) angstrom, angle C-C N 178(1)angstrom. Compound III: space group P2(1)/n, a = 7.3016(8) angstrom, b = 7.8879(9) angstrom, c = 22.336(2) angstrom, beta = 96.107(2)angstrom, V = 1279.1(2) angstrom(3), Z = 4, R-hk1 = 0.0808, N-Cl = 1.77(2) angstrom.

  DOI：

  10.1134/s0036023608070139