[Cu(tris(3-mesitylpyrazol-1-yl)methane)(CO)]PF6 | 1000872-12-7

• 英文名称: [Cu(tris(3-mesitylpyrazol-1-yl)methane)(CO)]PF6
• CAS: 1000872-12-7
• 化学式: C₃₈H₄₀CuN₆O*F₆P
• 分子量: 805.285
• InChiKey: XWUIRKNCYVWLTG-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Cu(tris(3-mesitylpyrazol-1-yl)methane)(NCMe)]PF6*NCMe 、 一氧化碳 以 二氯甲烷 为溶剂， 生成 [Cu(tris(3-mesitylpyrazol-1-yl)methane)(CO)]PF6
  参考文献：
  名称：

  Catalytic Carbon−Hydrogen Bond Functionalization in an Ionic Liquid Medium

  摘要：

  The functionalization of unreactive C-H bonds of several hydrocarbons has been achieved at room temperature by the formal insertion of carbene/CHCO2Et units (from ethyl diazoacetate) into such bonds, using copper-based catalysts in a biphasic reaction medium (ionic liquid-hydrocarbon). Catalyst and product separation has been carried out easily, and the recycle of the catalyst for five cycles has been achieved without any loss of catalytic activity.

  DOI：

  10.1021/om700822a