[Cu(acac)(Rc-dpm)] | 1262871-13-5

• 英文名称: [Cu(acac)(Rc-dpm)]
• 英文别名: [copper(II)(acetylacetonate)(ruthenocenyl(dipyrromethene))]
• CAS: 1262871-13-5
• 化学式: C₂₄H₂₂CuN₂O₂Ru
• 分子量: 535.067
• InChiKey: OTEHLTYYUBRQOP-BIPGZBTMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper acetylacetonate 、 [ruthenocenyl(dipyrromethane)] 在 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) 作用下， 以 甲醇 、 乙腈 为溶剂， 以42.2%的产率得到[Cu(acac)(Rc-dpm)]
  参考文献：
  名称：

  Heterometallic complexes derived from ruthenocene-functionalized dipyrromethenes

  摘要：

  A new ligand based on a ruthenocene moiety appended by a diyrromethene (Rc-dpm) was synthesized. Two copper complexes, Cu(Rc-dpm)(2) (3) and Cu(Rc-dpm)acac (4), and one cobalt complex, Co(Rc-dpm)(3), 5, were prepared from the ligand. These complexes were characterized by a combination of UV-Vis spectroscopy, elemental analysis, and X-ray crystallography. Copper(II) complex 3 was found to be coordinated by two dipyrromethene ligands in a distorted square planar environment around the copper while complex 4 had one dipyrromethene ligand and an acac coordinated in a nearly idealized square planar copper geometry. The cobalt(III) complex 5 has an octahedral geometry around the cobalt via the coordination of three dipyyromethene ligands. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.08.020