[(η5-C6H6(CH2CO(t)Bu)Mn(CO)3] | 81857-37-6

• 英文名称: [(η5-C6H6(CH2CO(t)Bu)Mn(CO)3]
• CAS: 81857-37-6
• 化学式: C₁₅H₁₇MnO₄
• 分子量: 316.236
• InChiKey: SAMUNYJLXILWAH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η5-C6H6(CH2CO(t)Bu)Mn(CO)3] 、 溶剂黄146 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Photochemical Rearomatization and Dearomatization of Tricarbonyl(η⁵-cyclohexadienyl)manganese Complexes

  摘要：

  Photoirradiation of the tricarbonyl(eta(5)-cyclohexadienyl)manganese complexes 2 in dichloromethane or cyclohexane leads to the formation of the rearomatization products 3 in high yield, while photoirradiation of 2 in acetonitrile or dimethylformamide results in 3 and deaxomatization products 5 and 6 with the ratio 1(5 + 6) of ca. 1:1. In the presence of acetic acid the photochemical reaction of 2 both in dichloromethane and in acetonitrile exclusively yields 5 and 6. The photochemical reaction of 2 might be of significant utility in the synthesis of functionalized arenes and substituted cyclohexadienes.

  DOI：

  10.1021/om050953b
• 作为产物：
  描述：

  (η6-benzene)manganese tricarbonyl perchlorate 以 乙醚 、 二氯甲烷 为溶剂， 以50%的产率得到[(η5-C6H6(CH2CO(t)Bu)Mn(CO)3]
  参考文献：
  名称：

  Photochemical Rearomatization and Dearomatization of Tricarbonyl(η⁵-cyclohexadienyl)manganese Complexes

  摘要：

  Photoirradiation of the tricarbonyl(eta(5)-cyclohexadienyl)manganese complexes 2 in dichloromethane or cyclohexane leads to the formation of the rearomatization products 3 in high yield, while photoirradiation of 2 in acetonitrile or dimethylformamide results in 3 and deaxomatization products 5 and 6 with the ratio 1(5 + 6) of ca. 1:1. In the presence of acetic acid the photochemical reaction of 2 both in dichloromethane and in acetonitrile exclusively yields 5 and 6. The photochemical reaction of 2 might be of significant utility in the synthesis of functionalized arenes and substituted cyclohexadienes.

  DOI：

  10.1021/om050953b

文献信息

• Synthesis and electrophilic reactivity of dicarbonylnitrosyl(cyclohexadienyl)manganese cations: double nucleophilic addition to coordinated arenes
  作者：Young Keun Chung、D. A. Sweigart、Neil G. Connelly、John B. Sheridan

  DOI：10.1021/ja00294a032

  日期：1985.4

  Synthese des cations (cyclohexadienyl)Mn(CO)(NO)L + par traitement de (cyclohexadienyl)Mn(CO) 2 L (L=CO, PBu 3 ) avec NOPF 6 . Mecanisme des reactions de ces cations avec les nucleophiles

  合成这些脱阳离子（环己二烯基）Mn（CO）（NO）L + 脱（环己二烯基）Mn(CO) 2 L (L=CO, PBu 3 ) avec NOPF 6 。亲核试剂减少阳离子的反应机理
• Chung, Young Ktun; Wlllard, Paul G.; Swelgart, Dwight A., Organometallics, <hi>1982</hi>, vol. 1, # 8, p. 1053 - 1056
  作者：Chung, Young Ktun、Wlllard, Paul G.、Swelgart, Dwight A.

  DOI：——

  日期：——