| 914499-24-4

• CAS: 914499-24-4
• 化学式: C₆₈H₁₀₄Al₂MgN₄O₄
• 分子量: 1119.87
• InChiKey: UILHRHDHUMQEGN-KJUMRZLUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [((2,6-(isopropyl)2C6H3)NC(CH3)CHC(CH3)N(2,6-(isopropyl)2C6H3))Al(methyl)OH] 、 magnesium bis(hexamethyldisilazide) 以 四氢呋喃 、 正己烷 为溶剂， 生成
  参考文献：
  名称：

  Soluble Molecular Compounds with the Mg−O−Al Structural Motif:  A Model Approach for the Fixation of Organometallics on a MgO Surface

  摘要：

  We report a facile route to the molecular compounds with the Mg-O-Al structural motif. The reaction of Mg[N(SiMe3)2]2 (1) with a stoichiometric amount of LAlOH(Me) (2) [L = CH{(CMe)(2,6-iPr2C6H3N)}2] in THF/n-hexane at 0 degrees C results in the formation of the heterobimetallic compound (Me3Si)2NMg(THF)2-O-Al(Me)L (3) in high yield. The similar reaction of 1 equiv of Mg[N(SiMe3)2]2 and 2 equiv of LAlOH(Me) results in the formation of trimetallic compound L(Me)Al-O-Mg(THF)2-O-Al(Me)L (4). Structural analyses of 3 and 4 have been carried out, revealing the presence of the Mg-O-Al motif. A tentative assignment of the Mg-O-Al vibrations has been made and was supported by calculations.

  DOI：

  10.1021/ja064460p