Photosubstitution in some cyanide complexes of chromium(III)(1)
作者:Adam Marchaj、Zofia Stasicka
DOI:10.1016/s0277-5387(00)87098-9
日期:1983.1
Photosubstitution by OH− ligand was concluded from a photochemical study of the [Cr(CN)6]3− and [Cr(CN)5OH]3− complexes in alkaline medium. Photoaccelerated aquation was found to proceed in the case of aquocyanochromates(III): [Cr(CN)5H2O]2− and [Cr(CN)3(H2O)3].