| 281225-74-9

• CAS: 281225-74-9
• 化学式: C₂₃H₂₆ClN₃PPtS₂*Cl
• 分子量: 705.571
• InChiKey: YLRJJDDYULHTDX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 sodium bicarbonate 作用下， 以 甲醇 、 氯仿 为溶剂， 生成 (η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate
  参考文献：
  名称：

  (η³-Allyl-2κ³C)(chloro-1κCl)(μ-N,N′-diethyldithioxamidato-1:2κ⁴S,S′:N,N′)[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate

  摘要：

  The title compound, [PdPtCl(C3H5)(C6H10N2S2)(C17H14NP)].- CHCl3, was obtained by deprotonation of the initial platinum(II) complex of the dithioxamide and subsequent reaction with [Pd(eta(3)-C3H5)(mu-Cl)](2). Both metal atoms exhibit a square-planar coordination geometry, with the two planes forming a dihedral angle of 21.7 (2)degrees. The dithioxamide bis-chelating bridge is flat.

  DOI：

  10.1107/s0108270102006303
• 作为产物：
  描述：

  cis-[Pt(DMSO)(2-diphenylphosphinopyridine)Cl2] 、 1,2-二(乙基氨基)乙烷-1,2-二硫酮 以 氯仿 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  (η³-Allyl-2κ³C)(chloro-1κCl)(μ-N,N′-diethyldithioxamidato-1:2κ⁴S,S′:N,N′)[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate

  摘要：

  The title compound, [PdPtCl(C3H5)(C6H10N2S2)(C17H14NP)].- CHCl3, was obtained by deprotonation of the initial platinum(II) complex of the dithioxamide and subsequent reaction with [Pd(eta(3)-C3H5)(mu-Cl)](2). Both metal atoms exhibit a square-planar coordination geometry, with the two planes forming a dihedral angle of 21.7 (2)degrees. The dithioxamide bis-chelating bridge is flat.

  DOI：

  10.1107/s0108270102006303

文献信息

• Synthesis, Stereochemistry, and Solution Dynamics of Heterobimetallic Complexes with Metals Connected by Dithioxamides in κ-S,S‘ κ-N,N‘ Binucleation Mode. The Molecular Structure of [2-(Diphenylphosphino)pyridine-Pt-Cl-(<i>μ</i>-<i>N</i>,<i>N</i>‘- dibenzyldithioxbisamidato-κ-<i>S</i>,<i>S</i>‘-Pt-κ-<i>N</i>,<i>N</i>‘-Pd)(<i>η</i>³-allyl)Pd]
  作者：Santo Lanza、Giuseppe Bruno、Francesco Nicolò、Archimede Rotondo、Rosario Scopelliti、Enrico Rotondo

  DOI：10.1021/om991008o

  日期：2000.6.1

  S}-phenylethyl, 9. These complexes are chiral; hence, 7 and 8 have been synthesized as racemates, and 9 as an equimolar diastereomeric mixture owing to the optically pure S}-phenylethyl substituent. Upon warming, 7 and 8 racemize, and 9 epimerizes. The isomerization processes may be explained by a mechanism that involves (a) breaking of one of the two Pd−N bonds; (b) rotation around the remaining Pd−N

  dithioxamide络合物的脱卤化氢（PN）CLPT（H 2 - [R 2 Ñ 2 c ^ 2小号2）+（CL -）}（PN = 2-（二苯基膦基）吡啶; H 2 - [R 2 Ñ 2 c ^ 2小号2 =二次dithioxamides ，H 2 DTO，R =乙基，1； R =苄基，2； R = S }-苯乙基，3）生成二硫代氨基甲酸酯[（PN）Cl] PT（HR 2 N 2 C 2 S 2）]（心率2 N2 c ^ 2小号2 - = dialkyldithioxamidate，HDTO）4 - 6，其可以作为配体（动作络合物作为配位体）。实际上，去质子化后，他们可以很容易促进[钯（的氯桥分解反应η 3 -烯丙基）（μ -Cl ）] 2导致式双核配合物[（PN）CLPT（μ -R 2 Ñ 2 Ç 2 š 2 -κ-小号，小号-PT-κ- ñ，ñ -Pd）的Pd（η 3 -烯丙基）];