cyanotricarbonyl(4,7-dimethyl-1,10-phenanthroline)rhenium(I) | 135733-41-4

• 英文名称: cyanotricarbonyl(4,7-dimethyl-1,10-phenanthroline)rhenium(I)
• 英文别名: Re(Me₂phen)(CO)₃(CN)；Re(4,7-dimethyl-1,10-phenanthroline)(CO)₃(CN)
• CAS: 135733-41-4
• 化学式: C₁₈H₁₂N₃O₃Re
• 分子量: 504.519
• InChiKey: MWWKSMRUJXMMIL-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  cyanotricarbonyl(4,7-dimethyl-1,10-phenanthroline)rhenium(I) 、 三(五氟苯基)硼烷 以 二氯甲烷 为溶剂， 以52%的产率得到isocyanotris(pentafluorophenyl)boratotricarbonyl(4,7-dimethyl-1,10-phenanthroline)rhenium(I)
  参考文献：
  名称：

  A Simple Design for Strongly Emissive Sky-Blue Phosphorescent Neutral Rhenium Complexes: Synthesis, Photophysics, and Electroluminescent Devices

  摘要：

  A simple design strategy for a new class of stable, vacuum-sublimable, and strongly emissive sky-blue neutral phosphorescent Re(I) phenanthroline complexes {Re(R(2)phen)(CO)(3)[CNB(C6F5)(3)]} is reported. These complexes show intense bluish green emission in CH2Cl2 solution with the highest emission quantum yield and bluest emission ever reported for the neutral Re(I) amine complexes. In the solid state, they display sky-blue emission. The electroluminescent properties of devices containing these complexes have also been investigated.

  DOI：

  10.1021/cm4038654
• 作为产物：
  描述：

  potassium cyanide 、 [Re(Me₂phen)(CO)₃(MeCN)]OTf 以 乙醇 、 水 为溶剂， 反应 16.0h， 以68%的产率得到cyanotricarbonyl(4,7-dimethyl-1,10-phenanthroline)rhenium(I)
  参考文献：
  名称：

  A Simple Design for Strongly Emissive Sky-Blue Phosphorescent Neutral Rhenium Complexes: Synthesis, Photophysics, and Electroluminescent Devices

  摘要：

  A simple design strategy for a new class of stable, vacuum-sublimable, and strongly emissive sky-blue neutral phosphorescent Re(I) phenanthroline complexes {Re(R(2)phen)(CO)(3)[CNB(C6F5)(3)]} is reported. These complexes show intense bluish green emission in CH2Cl2 solution with the highest emission quantum yield and bluest emission ever reported for the neutral Re(I) amine complexes. In the solid state, they display sky-blue emission. The electroluminescent properties of devices containing these complexes have also been investigated.

  DOI：

  10.1021/cm4038654