[(2,6-difluorophenylaminopyridinato)Ti2Cl6] | 1040086-64-3

• 英文名称: [(2,6-difluorophenylaminopyridinato)Ti2Cl6]
• CAS: 1040086-64-3
• 化学式: C₂₂H₁₄Cl₆F₄N₄Ti₂
• 分子量: 718.852
• InChiKey: MEZGENZXEHGTDZ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(2,6-difluorophenylamino)pyridine 、 四氯化钛 在 NaH 作用下， 以 乙醚 、 甲苯 为溶剂， 以96%的产率得到[(2,6-difluorophenylaminopyridinato)Ti2Cl6]
  参考文献：
  名称：

  Synthesis, characterization and ethylene polymerization activity of titanium aminopyridinato complexes

  摘要：

  Three titanium complexes derived from 2-(2,6-difluoroanilino) pyridine and 2-(2- chloroanilino) pyridine were synthesized and characterized by X-ray diffraction or spectroscopic methods. All titanium complexes have been used to catalyze the polymerization of ethylene in the presence of MAO as cocatalyst. The mono(2,6- difluorophenylaminopyridinato) titanium catalyst was found to be more active in ethylene polymerization than the bis(2,6- difluorophenylaminopyridinato) and bis(2- chlorophenylaminopyridinato) titanium catalysts. ortho-Halogens disturbed the beta-elimination transition state of ethylene polymerization and formed higher molar mass polyethylene than their unhalogenated congener. Due to fluxionality, the bis(2- chlorophenylaminopyridinato) titanium catalyst formed broader molar mass distribution than the bis(2,6- difluorophenylaminopyridinato) titanium catalysts. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.11.028