[Os3Fe2(μ(4)-S)(μ(3)-Te)(CO)17] | 306974-21-0

• 英文名称: [Os3Fe2(μ(4)-S)(μ(3)-Te)(CO)17]
• CAS: 306974-21-0
• 化学式: C₁₇Fe₂O₁₇Os₃STe
• 分子量: 1318.14
• InChiKey: WPXSEVFOFDPRNJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Os3Fe2(μ(4)-S)(μ(3)-Te)(CO)17] 以 苯 为溶剂， 生成 [Os3(μ(3)-S)(μ(3)-Te)(CO)9]
  参考文献：
  名称：

  Synthesis and characterisation of [Fe2M3(μ4-E)(μ3-E′)(CO)17] and [Os3(μ3-E)(μ3-E′)(CO)9] (M=Os or Ru; E=S, Se, Te; E′=Se, Te)

  摘要：

  A set of new chalcogen-bridged mixed metal clusters [Fe2Os3(mu(4)-E)(mu(3)-E')(CO)(17)] (2, EE' = SeTe; 3, EE' = STe; 4, EE' = Se-2; 5 EE' = SSe) and [Fe2Ru3(mu(4)-E)(mu(3)-E')(CO)(17)] (12, EE' = SeTe; 13, EE' = STe; 14, EE' = Se-2; 15, EE' = SSe) has been synthesised by facile methods. Thermolysis or photolysis of compounds 2, 3 and 5 afforded the new triosmium mixed chalcogenide clusters [Os-3(mu(3)-E)(mu(3)-E)(CO)(9)] (7, EE' = SeTe; 8, EE' = STe; 10, EE' = SSe). All new compounds were characterised by IR and H-1-, Se-77- and Te-125-NMR spectroscopy. Clusters 8, 9 and 12 were structurally characterised by single crystal X-ray diffraction methods. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00344-2
• 作为产物：
  描述：

  undecacarbonyl(acetonitrile)triosmium 、 Fe2(CO)6(μ-STe)2 以 苯 为溶剂， 以50%的产率得到[Os3Fe2(μ(4)-S)(μ(3)-Te)(CO)17]
  参考文献：
  名称：

  Synthesis and characterisation of [Fe2M3(μ4-E)(μ3-E′)(CO)17] and [Os3(μ3-E)(μ3-E′)(CO)9] (M=Os or Ru; E=S, Se, Te; E′=Se, Te)

  摘要：

  A set of new chalcogen-bridged mixed metal clusters [Fe2Os3(mu(4)-E)(mu(3)-E')(CO)(17)] (2, EE' = SeTe; 3, EE' = STe; 4, EE' = Se-2; 5 EE' = SSe) and [Fe2Ru3(mu(4)-E)(mu(3)-E')(CO)(17)] (12, EE' = SeTe; 13, EE' = STe; 14, EE' = Se-2; 15, EE' = SSe) has been synthesised by facile methods. Thermolysis or photolysis of compounds 2, 3 and 5 afforded the new triosmium mixed chalcogenide clusters [Os-3(mu(3)-E)(mu(3)-E)(CO)(9)] (7, EE' = SeTe; 8, EE' = STe; 10, EE' = SSe). All new compounds were characterised by IR and H-1-, Se-77- and Te-125-NMR spectroscopy. Clusters 8, 9 and 12 were structurally characterised by single crystal X-ray diffraction methods. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00344-2