| 180568-94-9

• CAS: 180568-94-9
• 化学式: C₆₈H₆₂Cu₂P₄
• 分子量: 1130.23
• InChiKey: JARJVPYNLWBDKU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  二苯基甲氧基膦 、 copper(I) phenylacetylenide 以 二氯甲烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Photophysics and photochemical reactivities of organocopper(I) complexes. Crystal structure of [Cu₂(PPh₂Me)₄(µ,η¹-CCPh)₂]

  摘要：

  Dimeric [Cu-2(PPh(2)Me)(4)(mu,eta(1)-C=CPh)(2)] has been synthesized and crystallographically characterized; its photophysics together with those of other related organocopper(I) complexes, [Cu-2{2-C(SiMe(3))(2)C5H4N}(2)] and [{Cu(C(6)H(2)Me3-2,4,6)}(5)] have been studied and Stern-Volmer quenching data of the phosphorescent state of the pyridine complex with organic halides are suggestive of a charge-transfer mechanism with a high driving-force regime.

  DOI：

  10.1039/dt9960002889