[MeZnOPr]4 | 1088384-12-6

• 英文名称: [MeZnOPr]4
• CAS: 1088384-12-6
• 化学式: C₁₆H₄₀O₄Zn₄
• 分子量: 558.051
• InChiKey: GODLVBAOGBCKBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [MeZnOPr]4 、 水 以 四氢呋喃 为溶剂， 生成 zinc(II) oxide
  参考文献：
  名称：

  Nucleation and Growth of ZnO in Organic Solvents - an in Situ Study

  摘要：

  ZnO is a metal oxide material which possesses versatile properties and applications. Therefore, the target-oriented preparation of ZnO has become a major issue. Many preparation techniques involve bottom-up methods from precursor solutions. In the current contribution, a special precursor system is described that enables a fine-control of kinetic parameters for the nucleation and growth of ZnO in various organic solvents. A large variety of analytical techniques could be applied in an in situ fashion to probe for the ZnO formation at all times and all length scales. Among the analytical techniques are UV/vis, Raman, Fluorescence, X-ray absorption, H-1 NMR-spectroscopy, dynamic light-scattering, and TEM. Three different regimes for nucleation and growth with different characteristics could be identified. Furthermore, the effect of different parameters on the resulting ZnO particle size was investigated.

  DOI：

  10.1021/ja804071h
• 作为产物：
  描述：

  丙醇 、 Dimethylzinc 以 甲苯 为溶剂， 生成 [MeZnOPr]4
  参考文献：
  名称：

  Nucleation and Growth of ZnO in Organic Solvents - an in Situ Study

  摘要：

  ZnO is a metal oxide material which possesses versatile properties and applications. Therefore, the target-oriented preparation of ZnO has become a major issue. Many preparation techniques involve bottom-up methods from precursor solutions. In the current contribution, a special precursor system is described that enables a fine-control of kinetic parameters for the nucleation and growth of ZnO in various organic solvents. A large variety of analytical techniques could be applied in an in situ fashion to probe for the ZnO formation at all times and all length scales. Among the analytical techniques are UV/vis, Raman, Fluorescence, X-ray absorption, H-1 NMR-spectroscopy, dynamic light-scattering, and TEM. Three different regimes for nucleation and growth with different characteristics could be identified. Furthermore, the effect of different parameters on the resulting ZnO particle size was investigated.

  DOI：

  10.1021/ja804071h