Metastable iron/sulfur clusters. The synthesis, electronic structure, and transformations of the [Fe6S6(L)6]3- clusters (L = Cl-, Br, I-, RS-, RO-) and the structure of [(C2H5)4N]3[Fe6S6Cl6]
Metastable iron/sulfur clusters. The synthesis, electronic structure, and transformations of the [Fe6S6(L)6]3- clusters (L = Cl-, Br, I-, RS-, RO-) and the structure of [(C2H5)4N]3[Fe6S6Cl6]
A new iron–sulphide cluster containing the ‘prismane’[Fe<sub>6</sub>(µ-S)<sub>6</sub>]<sup>3+</sup>core. Synthesis, structure, and properties of [Et<sub>4</sub>N]<sub>3</sub>[Fe<sub>6</sub>S<sub>6</sub>Cl<sub>6</sub>]
作者:M. G. Kanatzidis、W. R. Dunham、W. R. Hagen、D. Coucouvanis
DOI:10.1039/c39840000356
日期:——
The synthesis and structural (crystallographic and spectroscopic) characterization of the new Fe–S–Cl cluster [Fe6S6Cl6]3– is described.
描述了新的Fe–S–Cl团簇[Fe 6 S 6 Cl 6 ] 3–的合成和结构(晶体学和光谱学)表征。