| 156754-78-8

• CAS: 156754-78-8
• 化学式: C₅₄H₇₆Cl₂Cu₂N₂P₂
• 分子量: 1013.16
• InChiKey: XWHSICOWWVEZMM-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  乙腈 、 copper(l) chloride 、 1-(2,4,6-tri-t-butylphenyl)-2-phenyl-1-phosphaethene 以 二氯甲烷 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Mono- and bi-dentate phosphaalkene ligands: structures of their copper(I) chloride complexes

  摘要：

  While the reaction of the monophosphaalkene [(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl]-benzene (L2) with copper(I) chloride ed to a dimeric complex [Cu2Cl2L22(NCMe)2] 1, use of the diphosphaalkene 1,3-bis[(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl]benzene (L1) gave rise to a tetrameric complex [Cu4Cl4L12].3EtOH 2. The crystal structures of the complexes have been determined and indicate that 1 is a centrosymmetric dimer with tetrahedrally co-ordinated copper(I) centres, whereas 2 adopts a 'cubane-like' structure with pairs of copper atoms bridged by different L1 units.

  DOI：

  10.1039/dt9940001685