lithium (1-methyl-2-methoxy)ethyl 3-ketobutanoate | 146523-40-2

• 英文名称: lithium (1-methyl-2-methoxy)ethyl 3-ketobutanoate
• CAS: 146523-40-2
• 化学式: C₈H₁₃O₄*Li
• 分子量: 180.13
• InChiKey: CUSITJZTUUVNAM-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  cobalt(II) chloride hexahydrate 、 lithium (1-methyl-2-methoxy)ethyl 3-ketobutanoate 以 甲醇 、 丙酮 为溶剂， 生成 cobalt(II) ((1-methyl-2-methoxy)ethyl 3-ketobutanoate) dihydrate
  参考文献：
  名称：

  Preparation of cobalt(II) complexes of β-keto esters

  摘要：

  Using the ethyl. (-)-menthyl and (1-methyl-2-methoxy)ethyl esters of 3-keto-butanoic acid as model compounds, three procedures have been developed for preparing cobalt(II) complexes of beta-keto esters in non-aqueous media. These procedures involve the reaction between the lithium enolate, the caesium enolate and the trimethylsilyl enolate of the beta-keto ester with an appropriate cobalt(II) compound. All three procedures appear applicable to the preparation of other metal(II) complexes and to beta-diketones.

  DOI：

  10.1016/s0277-5387(00)83601-3