(C5H5)2Dy[H2N(CH2)3N=C(NHiPr)NiPr] | 1085430-10-9

• 英文名称: (C5H5)2Dy[H2N(CH2)3N=C(NHiPr)NiPr]
• CAS: 1085430-10-9
• 化学式: C₂₀H₃₃DyN₄
• 分子量: 492.009
• InChiKey: OPCIPPUZUPXNFQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Dy(tris(cyclopentadienyl)) 、 1,3-丙二胺 、 N,N'-二异丙基碳二亚胺 以 四氢呋喃 为溶剂， 生成 (C5H5)2Dy[H2N(CH2)3N=C(NHiPr)NiPr]
  参考文献：
  名称：

  Synthesis and structural characterizations of organolanthanide complexes with amino-tethered guanidinate ligand (C5H5)2Ln[H2N(CH2)3NC(NHiPr) NiPr)] (Ln=Yb, Y, Er, Dy)

  摘要：

  Reaction of N,N '-diisopropylcarbodiimide ((PrN)-Pr-i=C=(NPr)-Pr-i) with H2N(CH2)(3)NH2 and (C5H5)(3)Ln, give (C5H5)(2)Ln[H2N(CH2)(3) N=C((NHPr)-Pr-i) (NPr)-Pr-i)] in high yields, indicating that the N-H bonds of one NH2 group readily add to the C=N double bonds of carbodiimide and one cyclopentadienyl group is eliminated to construct a novel amino-tethered guanidinate anionic ligand [H2N(CH2)(3)N=C((NHPr)-Pr-i)(NPr)-Pr-i)](-). (c) 2007 Published by Elsevier B.V.

  DOI：

  10.1016/j.inoche.2007.07.013