[Os(η(6)-C6H6)(η(4)-C6F6)] | 158309-68-3

• 英文名称: [Os(η(6)-C6H6)(η(4)-C6F6)]
• CAS: 158309-68-3
• 化学式: C₁₂H₆F₆Os
• 分子量: 454.37
• InChiKey: VCTJXBFOQVGMAC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  锇 、 六氟苯 以 neat (no solvent) 为溶剂， 以3.4%的产率得到[Os(η(6)-C6H6)(η(4)-C6F6)]
  参考文献：
  名称：

  Synthesis of new η⁴-hexafluorobenzene complexes of ruthenium and osmium from atoms of the metals: crystal structure of [Ru(η⁶-C₆H₃Me₃-1,3,5)(η⁴-C₆F₆)]

  摘要：

  Condensation of ruthenium or osmium atoms with mixtures of hexafluorobenzene and a second arene at -196-degrees-C has given the novel compounds [M(eta6-arene)(eta4-C6F6)] (M = Ru or Os; arene = C6H3Me3-1,3,5, C6H4Me2-1,3 or C6H6), these being further examples of compounds with a partially co-ordinated hexafluorobenzene ligand. The hapticity of the arene rings was determined from their proton and fluorine NMR spectra. This was confirmed for the specific case of [Ru(eta6-C6H3Me3-1,3,5)(eta4-C6F6)] by an X-ray crystallographic study. The bis(hexafluorobenzene) compounds could not be prepared.

  DOI：

  10.1039/dt9940002251