Br(CO)3Re(μ-phen-5-(NH-CS-NH)-5-phen)Re(CO)3Br | 1396790-77-4

• 英文名称: Br(CO)3Re(μ-phen-5-(NH-CS-NH)-5-phen)Re(CO)3Br
• CAS: 1396790-77-4
• 化学式: C₃₈H₂₂Br₂N₈O₆Re₂S₂
• 分子量: 1283.0
• InChiKey: NTJWOVADYBQHRH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  fac-Re(CO)3(1,10-phenanthrolin-5-isothiocyanate) 、 对苯二胺 以 丙酮 为溶剂， 反应 24.0h， 以60%的产率得到Br(CO)3Re(μ-phen-5-(NH-CS-NH)-5-phen)Re(CO)3Br
  参考文献：
  名称：

  Neutral Re(I) complexes for anion sensing

  摘要：

  Anion sensing properties toward F-, OAc- and H2PO4- were studied for new mononuclear and dinuclear Re(I) complexes based on a five-substituted phenanthroline moiety bearing a thiourea hydrogen-bonding receptor. Log(K-1:1) values between 4 and 6 were obtained for the complexes by UV-vis titrations and between 3 and 5 by H-1 NMR titrations. The effect of hydrogen-bonding versus deprotonation of the thiourea receptor upon addition of the anions was also evaluated by UV-vis and NMR titration techniques. In addition, an X-ray structure of the Re(I) precursor complex is reported and the chirality of the mononuclear and dinuclear complexes is discussed.

  DOI：

  10.1080/10610278.2012.691500