1,7-C2B10H11-9-HgOCOCF3 | 59993-35-0

• 英文名称: 1,7-C2B10H11-9-HgOCOCF3
• CAS: 59993-35-0
• 化学式: C₄H₁₁B₁₀F₃HgO₂
• 分子量: 456.825
• InChiKey: FEOVTXCOGZSMEC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,7-C2B10H11-9-HgOCOCF3 在 potassium trifluoroacetate 作用下， 以 丙酮 为溶剂， 以70%的产率得到bis(1,7-dicarba-closo-dodecaboran(12)-yl-1)mercury
  参考文献：
  名称：

  Electrochemical symmetrization of carboranylmercury salts

  摘要：

  DOI：

  10.1016/0022-328x(85)88023-2
• 作为产物：
  描述：

  1,7-dicarba-closo-dodecaborane(12) 、 mercury(II) trifluoroacetate 生成 1,7-C2B10H11-9-HgOCOCF3
  参考文献：
  名称：

  Zakharkin, L. I.; Pisareva, I. V., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1977, p. 1747 - 1750

  摘要：

  DOI：

文献信息

• Synthesis of compounds with polymetallic chains including boron atoms of a carborane cage
  作者：M.N. Bochkarev、E.A. Fedorova、G.A. Razuvaev、V.I. Bregadze、V.Ts. Kampel

  DOI：10.1016/0022-328x(84)80064-9

  日期：1984.4

  by treatment of the digermane (C6F5)3GeGeEt3, with B-mercurated derivatives of the carboranes m-C2H2B10H9HgX (X = Cl, OCOCF3) and m-C2H2B10H8(HgOCOCF3)2. Treatment of HGe(C6F5)2Ge(C6F5)2H with methyl(m-carboran-9-yl)mercury resulted in a compound with a B-Hg-Ge-Ge-Hg-B chain containing two carborane cages at the ends of the chain. The compound prepared can take part in oxidative insertion of Pt(PPh3)n

  与B-汞的Ge或Ge-HG-BB-HG-葛链，其中硼原子是一个碳硼烷笼的成员已经制备通过处理乙锗烷的（C化合物6 ˚F 5）3 GeGeEt 3，用乙-碳硼烷的巯基衍生物m -C 2 H 2 B 10 H 9 HGX（X = Cl，OCOCF 3）和m -C 2 H 2 B 10 H 8（HGOCOCF 3）2。HGe（C 6 F 5）2的处理葛（C 6 ˚F 5）2 H带甲基（米-carboran -9-基）汞导致与含有两个碳硼烷笼在链的末端的B汞-Ge系的Ge-HG-B链的化合物。制备的化合物可参与Pt（PPh 3）n（n = 3,4）的氧化插入，得到B-HG-Pt-Ge，Ge-Pt-HG-BB-HG-Ge和B-HG链-Pt-Ge-Ge-Pt-HG-B。
• Thallation of carboranes
  作者：V.I. Bregadze、A.Ya. Usiatinsky、N.N. Godovikov

  DOI：10.1016/0022-328x(85)87322-8

  日期：1985.9

  The conditions of the preparation of boron—thallated 1,2-, 1,7- and 1,12-dicarba-closo-dodecaboranes(12) (trivial names “o-, m- and p-carboranes”) have been studied. It was shown that maximum yields of the products are attained when o- and m-carboranes are treated consecutively with equimolecular amounts of mercuric oxide and then thallium(III) trifluoroacetate or thallium(III) acetate sesquihydrate

  的硼thallated 1,2-，1,7-和1,12- dicarba-制剂的条件闭合碳（“俗名-dodecaboranes（12）ø - ，米-和p -carboranes”）进行了研究。结果表明，当所获得的产品的最大产率ø -和米-carboranes与等摩尔量的氧化汞，然后铊（III）连续处理三氟乙酸盐或铊（III）乙酸乙酯倍半水合物。应使用纯三氟乙酸作为溶剂。反应混合物中水的存在和反应混合物的过热导致硼化th化硼烷的收率降低和氧化硼烷的含量增加。
• Forging Unsupported Metal–Boryl Bonds with Icosahedral Carboranes
  作者：Liban M. A. Saleh、Rafal M. Dziedzic、Saeed I. Khan、Alexander M. Spokoyny

  DOI：10.1002/chem.201601292

  日期：2016.6.13

  metal‐boryl complexes to further our understanding of one of these elementary steps, oxidative addition. Structurally characterized examples of group 10 M−B bonds featuring icosahedral carboranes are completely unknown. Use of mercurocarboranes as a reagent to deliver M−B bonds saw divergent reactivity for platinum and palladium, with a Pt−B bond being isolated for the former, and a rare Pd−Hg bond being

  与可用于在芳族烃上安装官能团的多种金属催化交叉偶联方法相反，对于二十面体碳硼烷，目前尚没有可比较的各种方法，它们是富含硼的芳基的三维芳族类似物。部分原因是由于对碳硼烷交叉偶联基本步骤的了解有限。在这里，我们报告了我们在分离金属-硼基配合物方面的努力，以加深我们对这些基本步骤之一的认识，即氧化加成。10 M组的结构特征示例具有二十面体碳硼烷的-B键是完全未知的。使用巯基碳氧烷作为传递M-B键的试剂，发现铂和钯的反应性不同，前者分离出Pt-B键，而后者形成了罕见的Pd-Hg键。
• Deboronation of 9-substituted-ortho- and -meta-carboranes
  作者：Mark A. Fox、Kenneth Wade

  DOI：10.1016/s0022-328x(98)00881-x

  日期：1999.1

  A systematic study has been carried out of deboronation reactions of a series of icosahedral carborane derivatives bearing a variety of substituents on selected (generally antipodal) boron atoms. Reactions of the 9-substituted meta-carboranes, 9-R-1,7-C2B10H11 (R = OH, 4-MeC6H4, F, Cl, Br, I), with tetrabutylammonium fluoride hydrate (TBAFH) in refluxing THF gave nido-carborane salts containing a mixture of 1- and 6-R-7,9-C(2)B(9)H(<(11)over bar>) nido-anions. Regioselective deboronation occurred with the 9-halo-meta-carboranes, 9-X-1,7-C2B10H11 (X = F, Cl, Br, I), producing a 2:1 ratio mixture of nido 6-X-7,9-C(2)B(9)H(<(11)over bar>) and 1-X-7,9-C(2)B(9)H(<(11)over bar>). Calculated Mulliken charges at B2 and B3 of some 9-substituted-meta carboranes show that these vary in line with observed deboronation rates and product ratios in their reactions with TBAFH. The ortho-carborane derivative 9-I-1,2-C2B10H11 and TBAFH gave the tetrabutylammonium salt of the nido anion 5(6)-I-7,8-C(2)B(9)H(<(11)over bar>). The mercurated and thallated meta carboranes, 9-M-1,7-C2B9H11 (M = HgOCOCF3 and Tl(OCOCF3)(2)), with TBAFH underwent boron-metal bond cleavage to yield mainly the nido anion 7,9-C(2)B(9)H(<(12)over bar>). Multinuclear (B-11, C-13, H-1, F-19) NMR spectra of the carboranes have been recorded and assigned. (C) 1999 Elsevier Science S.A. All rights reserved.
• Thermal decomposition of bis-(9-o- and 9-m-carboranyl)mercury
  作者：L. I. Zakharkin、I. V. Pisareva

  DOI：10.1007/bf00956166

  日期：1983.5