| 1233221-22-1

• CAS: 1233221-22-1
• 化学式: C₅₀H₄₆FeP₂PtS₂
• 分子量: 1023.92
• InChiKey: CGDZJGNDDPLODI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [1,1'-bis(diphenylphosphino)ferrocene]platinum(II) chloride 、 3,5-二甲基苯硫酚 在 N(C₂H₅)3 作用下， 以 二氯甲烷 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  Synthesis, electrochemical properties and reactivity of [Fe(η5-C5H4PPh2)2]Pt(benzenethiolate)2 complexes: X-ray crystal structure of [Fe(η5-C5H4PPh2)2]Pt(SC6HF4)2

  摘要：

  Three heteroleptic Pt(II) complexes with 1,1'-bis(diphenylphosphino)ferrocene (dppf) and benzenemonothiolate (BzT) ligands Such as benzenethiolate (BT), 2,3,5,6-tetrafluorobenzenethiolate (TFBT) and 3,5-dimethylbenzenethiolate (DMBT), (dppf)Pt(BzT)(2), were synthesized from (dPPf)PtCl2 and the corresponding benzene-monothiols. X-ray structural analysis of (dppf)Pt(TFBT)(2) showed that the two TFBT ligands are parallel and in an anti-con formation with respect to a slightly distorted P2PtS2 plane. The redox properties of the three Pt(II) complexes are correlated with the electron-donating capability of the monothiolate ligands. The more-electronegative TFBT ligand induces a short Pt-P bond distance (2.273(2) angstrom), a large Pt-P coupling constant (J(Pt-P) = 3171 Hz) and a high oxidation potential (E-pa(3) = 1.355 V). A charge-transfer complex of (dppf)Pt(DMBT)(2) was prepared by the reaction with F4TCNQ and characterized. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.11.010