| 149972-70-3

• CAS: 149972-70-3
• 化学式: C₂H₃N*C₂₂H₂₂N₆O₆Sn
• 分子量: 626.216
• InChiKey: PXIUYVXJDSGDLY-FYGXJKBHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 四丁基氟化铵 以 氯仿 、 乙腈 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Tin(IV), germanium(IV) and silicon(IV) complexes of the dianion of 5, 14-dihydro-6,8,15,17-tetramethyldibenzo-[b,i][1,4,8,11]tetraazacyclotetradecine (H₂L): crystal structures of trans-Sn(L)Cl₂and trans-Sn(L)(NO₃)₂·MeCN

  摘要：

  The macrocyclic complexes M (L)X2 (H2L = 5,14-dihydro-6,8,15,17-tetramethyldibenzo[b,i] [1,4,8,11]-tetraazacyclotetradecine; M = Sn, X = Cl, Br or 1; M = Ge, X = Cl; M = Si, X = Cl) have been prepared by the reaction of the tetrahalide MX4 with HL (M = Sn or Ge) or Li2L (M = Si) under mild conditions. Treatment of Sn(L)Cl2 with AgNO3 produces Sn(L)(NO3)2, which in turn gives Sn(L)F2 upon reaction with [NBu4]F. X-Ray crystal structures of Sn(L)Cl2 and Sn(L)(NO3)2.MeCN reveal that the complexes retain the characteristic saddle-shaped configuration of the ligand but have adopted a trans geometry.

  DOI：

  10.1039/dt9930002101
• 作为产物：
  描述：

  trans-[Sn(5,14-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine(2-))Cl2] 、 乙腈 在 AgNO₃ 作用下， 以 氯仿 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Tin(IV), germanium(IV) and silicon(IV) complexes of the dianion of 5, 14-dihydro-6,8,15,17-tetramethyldibenzo-[b,i][1,4,8,11]tetraazacyclotetradecine (H₂L): crystal structures of trans-Sn(L)Cl₂and trans-Sn(L)(NO₃)₂·MeCN

  摘要：

  The macrocyclic complexes M (L)X2 (H2L = 5,14-dihydro-6,8,15,17-tetramethyldibenzo[b,i] [1,4,8,11]-tetraazacyclotetradecine; M = Sn, X = Cl, Br or 1; M = Ge, X = Cl; M = Si, X = Cl) have been prepared by the reaction of the tetrahalide MX4 with HL (M = Sn or Ge) or Li2L (M = Si) under mild conditions. Treatment of Sn(L)Cl2 with AgNO3 produces Sn(L)(NO3)2, which in turn gives Sn(L)F2 upon reaction with [NBu4]F. X-Ray crystal structures of Sn(L)Cl2 and Sn(L)(NO3)2.MeCN reveal that the complexes retain the characteristic saddle-shaped configuration of the ligand but have adopted a trans geometry.

  DOI：

  10.1039/dt9930002101