tricarbonyl(1-(((2-(carbomethoxy)pyrrolidino)carbonyl)methyl)-(1-4η)-4-methoxycyclohexa-1,3-dienyl)iron | 181234-82-2

• 英文名称: tricarbonyl(1-(((2-(carbomethoxy)pyrrolidino)carbonyl)methyl)-(1-4η)-4-methoxycyclohexa-1,3-dienyl)iron
• CAS: 181234-82-2；181377-88-8
• 化学式: C₁₈H₂₁FeNO₇
• 分子量: 419.214
• InChiKey: ZJIWDJFRAIFPCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 1-(((2-(carbomethoxy)pyrrolidino)carbonyl)methyl)4-methoxycyclohexa-1,3-diene 以 苯 为溶剂， 以40%的产率得到tricarbonyl(1-(((2-(carbomethoxy)pyrrolidino)carbonyl)methyl)-(1-4η)-4-methoxycyclohexa-1,3-dienyl)iron
  参考文献：
  名称：

  Asymmetric Tricarbonyliron Complexation of Cyclohexadiene Directed by Chiral Ester and Amide Auxiliaries

  摘要：

  Coupling of (+)-menthol, (+)-phenylethylamine and (-)-proline methyl ester with 4-methoxy-1-cyclohexa-2,4-dieneacetic acid gave the chiral ester 1 and amides 2 and 3, respectively, which were then isomerized into the 1,3-dienes. The diastereoselection induced by the chiral ester and amide auxiliaries during complexation with nonacarbonyliron was quite encouraging. The diastereomeric ratios of the ester- and amide-Fe(CO)(3) complexes formed were determined directly from the H-1 NMR integration of observable diastereotopic chemical shifts.

  DOI：

  10.1021/om960376e