P,P',C-[PtCl(1,3-C6H3(CON(PPh2)CH2Ph)2] | 694439-44-6

• 英文名称: P,P',C-[PtCl(1,3-C6H3(CON(PPh2)CH2Ph)2]
• CAS: 694439-44-6
• 化学式: C₄₆H₃₇ClN₂O₂P₂Pt
• 分子量: 942.292
• InChiKey: SCQRZPDFGKZEIQ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 1,3-C₆H₄(CON(PPh₂)CH₂Ph)2 以 二氯甲烷 为溶剂， 以85%的产率得到P,P',C-[PtCl(1,3-C6H3(CON(PPh2)CH2Ph)2]
  参考文献：
  名称：

  The preparation and coordination of 1,3-C6H4-{C(O)N(PPh2)CH2Ph}2 – a new multidentate ligand

  摘要：

  Reaction of isophthaloyl dichloride with two equivalents of benzylamine in the presence of Et3N gives N,N'-dibenzyl-1,3-isophthaldiamide which reacts with two equivalents of Ph2PCl, in the presence of n-BuLi at -78 degreesC to give 1,3-C6H4-{C(O)N(PPh2)CH2Ph}(2) (1). Reaction of 1 with [PtCl2(cod)] in dichloromethane gives the P,P',C tridentate bis-chelate [Pt(Cl){1,3-C6H4-{C(O)N(PPh2)CH2Ph}(2)}] (2), whilst reaction of 1 with two equivalents of [(C3H5)PdCl](2) in thf results in [{PdCl(C3H5)}(2) {1,3-C6H4-{C(O)N(PPh2)CH2Ph}(2)}] (3) in which the ligand bridges two palladium centres. The X-ray structures of 2 and 3 are reported. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.12.005