[Et4N][FeBr3(NO)] | 1264258-89-0

• 英文名称: [Et4N][FeBr3(NO)]
• CAS: 1264258-89-0
• 化学式: Br₃FeNO*C₈H₂₀N
• 分子量: 455.819
• InChiKey: LHWIZZSDMHEOCA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-pent-2-ene) lithium salt 、 [Et4N][FeBr3(NO)] 以 四氢呋喃 为溶剂， 以61%的产率得到[FeBr(NO)(CH(C(Me)N(2,6-diisopropylphenyl))2)]
  参考文献：
  名称：

  Chemistry of Nitrosyliron Complexes Supported by a β-Diketiminate Ligand

  摘要：

  Several nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6-diisopropylphenyl)NC(Me)](2)CH). The dinitrosyliron complexes [Fe(NO)(2)(Ar-nacnac)] (1) and (Bu4N)[Fe(NO)(2)(Ar-nacnac)] (2) react with [Fe-III(TPP)Cl] (TPP = tetraphenylporphine dianion) to generate [Fe-II(NO)(TPP)] and the corresponding mononitrosyliron complexes. The factors governing NO transfer with dinitrosyliron complexes (DNICs) 1 and 2 are evaluated, together with the chemistry of the related mononitrosyliron complex, [Fe(NO)Br(Ar-nacnac)] (4). The synthesis and properties of the related cobalt dinitrosyl [Co(NO)(2)-(Ar-nacnac)] (3) is also discussed for comparison to DNICs 1 and 2. The solid-state structures of several of these compounds as determined by X-ray crystallography are reported.

  DOI：

  10.1021/ic102300d