Ni(2,2'-bipyridine)3*[ZnCl(dihydrogenphosphate)3] | 858648-91-6

• 英文名称: Ni(2,2'-bipyridine)3*[ZnCl(dihydrogenphosphate)3]
• 英文别名: Ni(2,2'-Bipyridin)3*[ZnCl(dihydrogenphosphat)3]
• CAS: 858648-91-6
• 化学式: C₃₀H₂₄N₆Ni*ClH₆O₁₂P₃Zn
• 分子量: 919.055
• InChiKey: HZFKMENLRZJHPZ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  磷酸 、 2,2'-联吡啶 、 nickel(II) chloride hexahydrate 、 zinc(II) oxide 以 水 为溶剂， 以42%的产率得到Ni(2,2'-bipyridine)3*[ZnCl(dihydrogenphosphate)3]
  参考文献：
  名称：

  Synthesis and Characterization of a Molecular Zinc Phosphate Ni(2, 2'-bipy)3�[ZnCl(H2PO4)3]

  摘要：

  AbstractA new zinc phosphate cluster Ni(2, 2'‐bipy)3 · [ZnCl(H2PO4)3] (1) was obtained by the hydrothermal reaction of ZnO, H3PO4, NiCl2·6H2O, 2, 2'‐bipyridine(2, 2'‐bipy) and H2O in a molar ration of 1 : 1.9 : 0.5 : 1.5 : 126. The structure of 1 is made of [ZnCl(H2PO4)3] clusters that are separated by nickel complexes. The compound is novel in the sense that it is the first zinc phosphate cluster with metal complexes acting as structure‐directing agents. Crystal data: trigonal, space group = R3¯c (no. 167), a = 13.2407(3), c = 74.034(3) Å, V = 11240.5(6) Å3, Z = 12.

  DOI：

  10.1002/zaac.200400200