Mo(CO)3(1,10-phenanthroline)(HgCl)Cl | 105954-70-9

• 英文名称: Mo(CO)3(1,10-phenanthroline)(HgCl)Cl
• CAS: 105954-70-9
• 化学式: C₁₅H₈Cl₂HgMoN₂O₃
• 分子量: 631.676
• InChiKey: VGUWCIBDPSBBHK-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  Mo(CO)3(1,10-phenanthroline)(HgCl)Cl 、 tin(II) bromide 以 甲醇 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Reactivity of carbonyl complexes containing MoHg bonds; reaction of tin(II) halides with [Mo(CO)3(NN)(HgX)(X)] (NN = bpy, phen, dmp); crystal structure of [Mo(CO)3(dmp)(HgCl)(Cl)]

  摘要：

  Reaction of HgCl2 with [Mo(CO),(dmp)] (dmp = 2,9-dimethyl-1,10-phenanthroline) gives the heterobimetallic compound [MO(CO)3(dmp)(HgCl)(Cl)] (I), which gives rise to a new compound [Mo(CO)3(dmp)(HgCl)(Cl)] . 1/2(CH3)2CO (II) in acetone solution at low temperature. The crystal structure of I has been solved and the compound shown to be a capped trigonal prism containing Mo-Hg-Cl and Mo-Cl bonds. The reactions of the above and related heteronuclear complexes [MO(CO)3(NN)(HgX)(X)] [X = Cl, Br; NN = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen)] with tin (II) halides were studied. No insertion of the latter into the metal-metal or metal-halogen bonds were observed, with only bimetallic tricarbonyl complexes containing Mo-Hg bonds being isolated.

  DOI：

  10.1016/s0277-5387(00)80095-9
• 作为产物：
  描述：

  (η5-C5H5)Fe(CO)2HgMo(CO)3(1,10-phenanthroline)Cl 在 mercury dichloride 作用下， 以 丙酮 为溶剂， 生成 [Fe(η-cyclopentadienyl)(CO)2(HgCl)] 、 Mo(CO)3(1,10-phenanthroline)(HgCl)Cl
  参考文献：
  名称：

  The insertion of the [M(CO)3(NN)] fragments (M = Mo, W; NN = 2,2′-bipyridine; 1,10-phenanthroline; ethylenediamine) into the HgX (X = Cl, Br, I, N3, SCN) bonds of the [η5-C5H5Fe(CO)2(HgX)] complexes. Heterotrimetallic compounds with FeHgMX bondings

  摘要：

  DOI：

  10.1016/s0277-5387(00)80322-8

文献信息

• Reactivity of carbonyl complexes with MoHg bond. Interaction of tricarbonyl complexes of molybdenum(0) with thiourea and mercury chloride
  作者：A. Lopez、M. Panizo、M. Cano

  DOI：10.1016/0022-328x(86)80227-3

  日期：1986.9

  Addition of thiourea to (chloromercuri)molybdenum carbonyl complexes of the type NNMo(CO)3(HgCl)(Cl) (NN = 2,2′-bipyridine (bipy); 1,10-phenanthroline (phen); 2,9-dimethyl-1,10-phenanthroline (dmp)), give novel compounds in which the MoHg bond is retained.

  将硫脲添加到NNMo（CO）3（HgCl）（Cl）型（NN = 2,2'-联吡啶（bipy）; 1,10-菲咯啉（phen）; 2,9-二甲基-1,10-菲咯啉（dmp））产生保留MoHg键的新型化合物。