| 213414-95-0

• CAS: 213414-95-0
• 化学式: C₄H₈Cl₅OU*C₁₆H₃₆N
• 分子量: 729.869
• InChiKey: WOFMWBULUIISGO-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 四丁基氯化铵 、 氯化铀 以 四氢呋喃 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Chloride ion transfer during the U(IV)/U(III) reduction of UCl4 in tetrahydrofuran (THF), studied by cyclic voltammetry; synthesis and molecular structure of [NBu4][UCl5(THF)]

  摘要：

  The cyclic voltammogram of UCl4 in THF, with NBu4BPh4 as the supporting electrolyte, exhibits three cathodic waves at - 2.0, - 2.50 and - 2.70 V (versus Ag/AgCl); they are irreversible and of the EC type, with the formation of U (IV) anions [U2Cl9](-) and [UCl5](-). This proceeds by chloride ion transfer reactions from the electrogenerated anionic U(III) species. These reduction pathways were confirmed by electrochemical studies of the independently synthesized complexes [NBu4][U2Cl9]. 2.5THF (1), [NBu4][UCl5(THF)] (2) and [UCl3(THF)(2)][BPh4] (4). Complex 2 was characterized by its crystal structure; the anion displays an octahedral geometry with U-Cl = 2.60(1) Angstrom (average) and U-O = 2.42(1) Angstrom. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00126-1