| 156396-62-2

• CAS: 156396-62-2
• 化学式: C₂₈H₄₁Co₂Mo₂N₃OS₃
• 分子量: 841.717
• InChiKey: GOKRLERASWDABP-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Cp'2Mo2Co2(μ3-S)2(μ4-S)(CO)4 、 异氰酸叔丁酯 以 甲苯 为溶剂， 以84%的产率得到
  参考文献：
  名称：

  Reactions of Organic Isocyanides with the Mixed-Metal Clusters Cp'2Mo2Co2S3(CO)4 and Cp'2Mo2Co2S4(CO)2

  摘要：

  The bimetallic cluster Cp'2Mo2Co2S3(CO)4 reacts with tert-butyl or methyl isocyanide to give sequentially the mono-, di-, and trisubstituted clusters CP'2Mo2Co2S3(CO)4-x(L)x. The disubstituted derivatives are formed as a mixture of cis and trans isomers that are readily distinguished by their AMR spectra. Color changes and NMR evidence indicate that the adducts CP'2Mo2Co2S3(CO)4-x+1(L)x are formed prior to the loss of CO in the substitution reactions; the reluctance of the adduct with x = 4 to lose CO is invoked to explain the lack of formation of tetrasubstituted derivatives.

  DOI：

  10.1021/om00018a049