[Rh(COD)-N,N-bis[2-(diphenylphosphino)ethyl]benzenamine]BF4 | 352326-66-0

• 英文名称: [Rh(COD)-N,N-bis[2-(diphenylphosphino)ethyl]benzenamine]BF4
• CAS: 352326-66-0
• 化学式: BF₄*C₄₂H₄₅NP₂Rh
• 分子量: 815.484
• InChiKey: YNPPYUTXUPGYLG-ONEVTFJLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 、 N,N-bis[2-(diphenylphosphino)ethyl]-phenylamine 以 二氯甲烷 为溶剂， 以93%的产率得到[Rh(COD)-N,N-bis[2-(diphenylphosphino)ethyl]benzenamine]BF4
  参考文献：
  名称：

  Synthesis of new rhodium complexes with a hemilabile nitrogen-containing bis(phosphinite) or bis(phosphine) ligand. Application to hydroformylation of styrene

  摘要：

  Two new cationic rhodium(I) complexes with a hemilabile nitrogen-containing bis(phosphinite) or bis(phosphine) ligand have been prepared. P-31-NMR studies provide evidence that the Ligands are coordinated to the metal in P,P-bidentate mode, whereas for the bis(phoshine)-based ligand, a P,N,P-tridentate mode is also possible to be found at low temperatures. The complexes were applied to the hydroformylation of styrene and displayed a high chemoselectivity for aldehydes with a very good branched/linear ratio. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00701-x