| 149752-93-2

• CAS: 149752-93-2
• 化学式: C₆₂H₅₀N₄O₁₂Rh₂
• 分子量: 1248.91
• InChiKey: NODCJBROJFDYQG-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  、 di(rhodium)tetracarbonyl dichloride 以 苯 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  有机合成中的氨基硅烷。制备新的扩展卟啉配体和双金属过渡金属配合物。四吡咯大环二金属配合物的晶体结构

  摘要：

  The synthesis of pyrrole via carbocupration of gamma-amino-alpha,beta-acetylene esters, followed by reaction with acid chlorides, was shown to provide facile routes to new polyheterocyclic compounds and tetrapyrrolic macrocycles. New expanded porphyrins were obtained in two steps from the reaction of diacid dichlorides. The new tetrapyrrole macrocycle formed bimetallic complexes of Pd, Ni, and Rh. The X-ray crystal structure of the dirhodium complex revealed that the two rhodium atoms (Rh...Rh interatomic distance 4.38 angstrom) lie on the same side of the macrocycle. The latter adopted an overall saddle shape conformation to relieve strain within the molecule.

  DOI：

  10.1021/om00031a018