ferrocenyl(tert-butyl)dichlorogermane | 496975-50-9

• 英文名称: ferrocenyl(tert-butyl)dichlorogermane
• CAS: 496975-50-9
• 化学式: C₁₄H₁₈Cl₂FeGe
• 分子量: 385.64
• InChiKey: CUYNRMINHLOOBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ferrocenyl(tert-butyl)dichlorogermane 、 水 在 Et₃N 作用下， 以 乙醚 、 丙酮 为溶剂， 以93%的产率得到1,3-di-tert-butyl-1,3-diferrocenyldigermanoxanediol
  参考文献：
  名称：

  Hydrolysis of tert-Butyl and Phenyl Ferrocenyldichlorogermanes:  Characterization of Di-tert-butyldiferrocenyldigermoxanediol and 1,3,5-Triphenyl-1,3,5-triferrocenylcyclotrigermoxane

  摘要：

  The hydrolysis of ferrocenyl-tert-butyldichlorogermane (Fc(t-Bu)GeCl2, 1a, Fc = (eta(5)-C5H5)-Fe(eta(5) -C5H4)) resulted in the formation of the digermoxanediol [Fc(t-Bu)(HO)Ge](2)O (2), which in the solid state forms intermolecularly hydrogen-bonded dimeric 2a or double-chain 2b, structures dependent upon the solvent used for recrystallization. By contrast, similar hydrolysis of ferrocenylphenyldichlorogermane (FcPhGeCl(2), 1b) led to the formation of the cis and trans isomers of (FcPhGeO)(3) (3a and 3b) as a 1:4 ratio mixture, respectively. The cis isomer, 3a, can be converted to the thermodynamically more stable trans isomer, 3b. The molecular structures of 2a, 2b, 3a, and 3b have been determined by X-ray diffraction analysis.

  DOI：

  10.1021/om020788p
• 作为产物：
  描述：

  盐酸 、 [1]-tert-butylchlorogermyleneferrocenophane 以 乙醚 、 正己烷 为溶剂， 以80%的产率得到ferrocenyl(tert-butyl)dichlorogermane
  参考文献：
  名称：

  Hydrolysis of tert-Butyl and Phenyl Ferrocenyldichlorogermanes:  Characterization of Di-tert-butyldiferrocenyldigermoxanediol and 1,3,5-Triphenyl-1,3,5-triferrocenylcyclotrigermoxane

  摘要：

  The hydrolysis of ferrocenyl-tert-butyldichlorogermane (Fc(t-Bu)GeCl2, 1a, Fc = (eta(5)-C5H5)-Fe(eta(5) -C5H4)) resulted in the formation of the digermoxanediol [Fc(t-Bu)(HO)Ge](2)O (2), which in the solid state forms intermolecularly hydrogen-bonded dimeric 2a or double-chain 2b, structures dependent upon the solvent used for recrystallization. By contrast, similar hydrolysis of ferrocenylphenyldichlorogermane (FcPhGeCl(2), 1b) led to the formation of the cis and trans isomers of (FcPhGeO)(3) (3a and 3b) as a 1:4 ratio mixture, respectively. The cis isomer, 3a, can be converted to the thermodynamically more stable trans isomer, 3b. The molecular structures of 2a, 2b, 3a, and 3b have been determined by X-ray diffraction analysis.

  DOI：

  10.1021/om020788p