(η5-C5H5)Co(triphenylphosphine)[η1(N)-N(O)(ethyl)] | 78305-65-4

• 英文名称: (η5-C5H5)Co(triphenylphosphine)[η1(N)-N(O)(ethyl)]
• CAS: 78305-65-4
• 化学式: C₂₅H₂₅CoNOP
• 分子量: 445.447
• InChiKey: IERBITUGVHFUBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  在 PPh₃ 作用下， 以27%的产率得到(η5-C5H5)Co(triphenylphosphine)[η1(N)-N(O)(ethyl)]
  参考文献：
  名称：

  Direct observation of alkyl/nitrosyl migratory insertion in an organotransition metal complex

  摘要：

  DOI：

  10.1021/ja00402a079

文献信息

• Kinetics and mechanism of the formation of nitrosoalkane complexes by migratory insertion of coordinated nitric oxide into cobalt-carbon bonds
  作者：Wayne P. Weiner、Robert G. Bergman

  DOI：10.1021/ja00350a030

  日期：1983.6
• Conversion of (η⁵-C₅H₅)Co(PPh₃)₂ and Nitro Compounds to Mononuclear η¹(<i>N</i>)-Nitrosoalkyl and Dinuclear μ-η¹(<i>N</i>):η²(<i>N</i>,<i>O</i>)-Nitrosoaryl Complexes
  作者：Joseph M. O'Connor、Kevin D. Bunker

  DOI：10.1021/om034083e

  日期：2003.12.1

  The room-temperature reaction of (eta(5)-C5H5)Co(PPh3)(2) (5) with aliphatic nitro compounds, RNO2, where R = Me, Et, iPr, leads to formation of the corresponding eta(1)-nitroso derivatives (eta(5)-C5H5)Co(PPh3)[eta(1)(N)-N(O)R] (6-Me, R = Me; 6-Et, R = Et; 6-Pr, R = iPr). Aromatic nitro compounds, ArNO2, where Ar = -C6H5, -p-C(6)H(4)CdropCTMS, undergo reaction with 5 to give the mu-eta(1):eta(2) -nitroso derivatives, [(eta(5)-C5H5)CO](2)[mu-eta(1)(N):eta(2)(N,O)-N(O)R](2) (7-Ph, R = -C6H5; 7-Ar, R = -p-C(6)H(4)CdropCTMS). Complexes 6-Me and 7-Ar were -characterized by X-ray crystallographic analyses.