1,1,2,2-tetra-tert-butyl-1,2-distanna [2]ferrocenophane | 1256839-82-3

• 英文名称: 1,1,2,2-tetra-tert-butyl-1,2-distanna [2]ferrocenophane
• 英文别名: [Fe(η5,η5-C5H4Sn(tBu)2Sn(tBu)2C5H4)]
• CAS: 1256839-82-3
• 化学式: C₂₆H₄₄FeSn₂
• 分子量: 649.902
• InChiKey: YTNIWCUSWDYQNS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  环八硒 、 1,1,2,2-tetra-tert-butyl-1,2-distanna [2]ferrocenophane 以 氘代苯 为溶剂， 以45%的产率得到[Fe((η5-C5H4Sn(tBu)2)2Se)]
  参考文献：
  名称：

  Synthesis of a distanna [2]ferrocenophane and reactivity of [2]ferrocenophanes towards elemental sulfur and selenium

  摘要：

  Here we report the synthesis and crystal structure of a new [2]ferrocenophane [Fe(eta(5)-C(5)H(4))(2)(SntBu(2))(2)] with a sterically demanding distannanediyl bridge. The reactivity of the title compound towards selected main group elements was examined and in addition, this reactivity pattern was established for the related diboranediyl bridged [2] ferrocenophane [Fe(eta(5)-C(5)H(4))(2)(BNMe(2))(2)]. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.08.028
• 作为产物：
  描述：

  1,1'-dilithioferrocene N,N,N'N'-tetramethylethylenediamine 、 1,2-dichlorotetra-tert-butyldistannane 以 苯 为溶剂， 以74%的产率得到1,1,2,2-tetra-tert-butyl-1,2-distanna [2]ferrocenophane
  参考文献：
  名称：

  Synthesis of a distanna [2]ferrocenophane and reactivity of [2]ferrocenophanes towards elemental sulfur and selenium

  摘要：

  Here we report the synthesis and crystal structure of a new [2]ferrocenophane [Fe(eta(5)-C(5)H(4))(2)(SntBu(2))(2)] with a sterically demanding distannanediyl bridge. The reactivity of the title compound towards selected main group elements was examined and in addition, this reactivity pattern was established for the related diboranediyl bridged [2] ferrocenophane [Fe(eta(5)-C(5)H(4))(2)(BNMe(2))(2)]. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.08.028