[NHMe2C6H5][TaF6] | 1562379-19-4

• 英文名称: [NHMe2C6H5][TaF6]
• 英文别名: [NHMe₂C₆H₅][TaF₆]
• CAS: 1562379-19-4
• 化学式: C₈H₁₁N*F₆Ta*H
• 分子量: 417.128
• InChiKey: WHVFWXUWVSBVKX-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氟化钽(V) 、 N,N-二甲基苯胺 以 二氯甲烷 为溶剂， 反应 18.0h， 以13%的产率得到[NHMe2C6H5][TaF6]
  参考文献：
  名称：

  Reactions of TaF5 with activated arenes. Synthesis of [4-(OH)-3-(OCH3)C6H3CH(OH)][4-(OH)-3-(OCH3)C6H3CHO][TaF6], a rare example of protonated aldehyde

  摘要：

  The rare example of protonated aldehyde salt [4-(OH)-3-(OCH3)C6H3CH(=O-H)][4-(O-H)-3-(OCH3)C6H3-CHO][TaF6], 1, was isolated in the solid state by the reaction of 4-hydroxy-3-methoxybenzaldehyde (vanillin) with TaF5 in dichloromethane. The product 1 was characterized by X-ray diffraction and IR spectroscopy. The 1:1 reaction of TaF5 with N,N-dimethylaniline in CH2Cl2 cleanly afforded [TaF4(NMe2- C6H5)(2)][TaF6], 2, which was identified by NMR spectroscopy. Attempts of crystallization of 2 resulted in the isolation of the ammonium salt [NHMe2C6H5][TaF6], 3. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.12.015