[[Cu(4,4'-dipyridyl disulfide)2Cl2] | 667422-23-3

• 英文名称: [[Cu(4,4'-dipyridyl disulfide)2Cl2]
• CAS: 667422-23-3
• 化学式: C₂₀H₁₆CdCl₂N₄S₄
• 分子量: 623.954
• InChiKey: SATMHHQUROMDFN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,4'-联吡啶二硫醚 、 aqueous cadmium chloride 以 甲醇 、 水 、 乙腈 为溶剂， 以84%的产率得到[[Cu(4,4'-dipyridyl disulfide)2Cl2]
  参考文献：
  名称：

  Self‐Assembly of Three Cd ^II ‐ and Cu ^II ‐Containing Coordination Polymers from 4,4′‐Dipyridyl Disulfide

  摘要：

  AbstractThree new organic/inorganic coordination polymers, [{Cu(4‐DPDS)2(H2O)}·2NO3·3H2O]n (1), [{Cu(4‐DPDS)2(SO4)}· 1.5H2O·CH3OH]n (2), and [Cd(4‐DPDS)2Cl2]n (3), have been synthesized by using the flexible ligand 4,4′‐dipyridyl disulfide (4‐DPDS). Complex 1 crystallized in the Ibca space group: a = 10.5275(6), b = 20.2670(1), c = 27.235(1) Å, V = 5811.5(6) Å3, Z = 16. Complex 2 crystallized in the Pnna space group: a = 10.547(2), b = 14.201(2), c = 19.667(3) Å, V = 2945.8(8) Å3, Z = 8. Complex 3 crystallized in the P21/c space group: a = 7.6146(3), b = 18.2606(8), c = 9.3203(2) Å, β = 100.26(1)°, V = 1275.24(8) Å3, Z = 4. The three coordination polymers display a variety of structural architectures, ranging from double‐stranded chains (1) to two‐dimensional channels (2) and two‐dimensional, puckered, grid‐like arrays (3). Magnetic characterizations show that complex 1 exhibits antiferromagnetic interactions while 2 is ferromagnetic. Solid‐state fluorescence results reveal that 3 exhibits fluorescence emissions at 418 and 575 nm (λex = 314 nm). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

  DOI：

  10.1002/ejic.200300153