| 158595-01-8

• CAS: 158595-01-8
• 化学式: C₁₂H₁₃CrO₃*Li
• 分子量: 264.17
• InChiKey: IZOLOMMYLNEFMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氯化苯汞 以 四氢呋喃 为溶剂， 以21%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of trimetallic complexes [η5-RC5H4(CO)3E]2Hg (E = Cr, Mo, W ; R = Me, Et, n-Bu). Crystal structure of [η5-EtC5H4(CO)3Cr]2Hg

  摘要：

  The synthesis of six linear trimetallic compounds of the type [eta5-RC5H4 (CO)3E]2Hg (E = Cr, Mo, W; R = Me, Et, n-Bu), from phenylmercuric chloride and corresponding transition metal lithium salts [eta5-RC5H4(CO)3E]Li is described. The new compounds were characterized by elemental analysis, MS, IR and H-1 NMR spectroscopy and the structure of [eta5-EtC5H4(CO)3Cr]2Hg as determined by X-ray diffraction. The Cr-Hg-Cr skeleton of the molecule is diagonal with some departure from linearity and the coordination geometry around each chromium atom approximates to a square-based pyramid with one substituted cyclopentadienyl ring occupying the apical position.

  DOI：

  10.1016/s0277-5387(00)81500-4
• 作为产物：
  描述：

  1-(n-C4H9)C5H5 、 六羰基铬 在 n-butyl lithium 作用下， 以 二乙二醇二甲醚 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterization of trimetallic complexes [η5-RC5H4(CO)3E]2Hg (E = Cr, Mo, W ; R = Me, Et, n-Bu). Crystal structure of [η5-EtC5H4(CO)3Cr]2Hg

  摘要：

  The synthesis of six linear trimetallic compounds of the type [eta5-RC5H4 (CO)3E]2Hg (E = Cr, Mo, W; R = Me, Et, n-Bu), from phenylmercuric chloride and corresponding transition metal lithium salts [eta5-RC5H4(CO)3E]Li is described. The new compounds were characterized by elemental analysis, MS, IR and H-1 NMR spectroscopy and the structure of [eta5-EtC5H4(CO)3Cr]2Hg as determined by X-ray diffraction. The Cr-Hg-Cr skeleton of the molecule is diagonal with some departure from linearity and the coordination geometry around each chromium atom approximates to a square-based pyramid with one substituted cyclopentadienyl ring occupying the apical position.

  DOI：

  10.1016/s0277-5387(00)81500-4