[cis-Cl2((CH2OC6H4CH2SCH2)2CH2)Pd]*CH2Cl2 | 1144042-67-0

• 英文名称: [cis-Cl2((CH2OC6H4CH2SCH2)2CH2)Pd]*CH2Cl2
• CAS: 1144042-67-0
• 化学式: CH₂Cl₂*C₁₉H₂₂Cl₂O₂PdS₂
• 分子量: 608.773
• InChiKey: HZUQVXZHOAPQCQ-UHFFFAOYSA-L

物化性质

• 熔点：
  238-240 °C

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  甲醇 、 2,6-Dioxa-14,17-dithiatricyclo[17.4.0.07,12]tricosa-1(23),7,9,11,19,21-hexaene 、 [cis-Cl2((CH2OC6H4CH2SCH2)2CH2)Pd]*CH2Cl2 、 silver perchlorate 以 甲醇 为溶剂， 以0%的产率得到
  参考文献：
  名称：

  Bis(O2S2 macrocycle) complexes of palladium(II)

  摘要：

  Two isomeric dibenzo-O2S2 macrocycles L-1 and L-2 have been synthesised and their coordination chemistry towards palladium(II) has been investigated. Two-step approaches via reactions of 1:1-type complexes, [cis-Cl2LPd] (1a: L = L-1, 1b: L = L-2), with different O2S2 macrocycle systems (L-1 and L-2) have led to the isolation of the following bis(O2S2 macrocycle) palladium(II) complexes in the solid state: [Pd(L-1)(2)](ClO4)(2) (2a) and a mixture of [Pd(L-1)(2)](ClO4)(2) (2a) + [Pd(L-2)(2)](ClO4)(2) (2b). (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.019
• 作为产物：
  描述：

  potassium tetrachloropalladate(II) 、 二氯甲烷 、 2,5-Dioxa-13,17-dithiatricyclo[17.4.0.06,11]tricosa-1(23),6,8,10,19,21-hexaene 以 二氯甲烷 、 水 为溶剂， 以90%的产率得到[cis-Cl2((CH2OC6H4CH2SCH2)2CH2)Pd]*CH2Cl2
  参考文献：
  名称：

  Bis(O2S2 macrocycle) complexes of palladium(II)

  摘要：

  Two isomeric dibenzo-O2S2 macrocycles L-1 and L-2 have been synthesised and their coordination chemistry towards palladium(II) has been investigated. Two-step approaches via reactions of 1:1-type complexes, [cis-Cl2LPd] (1a: L = L-1, 1b: L = L-2), with different O2S2 macrocycle systems (L-1 and L-2) have led to the isolation of the following bis(O2S2 macrocycle) palladium(II) complexes in the solid state: [Pd(L-1)(2)](ClO4)(2) (2a) and a mixture of [Pd(L-1)(2)](ClO4)(2) (2a) + [Pd(L-2)(2)](ClO4)(2) (2b). (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.019