(η5-C5Me5Mo)2B5H7(μ3-OEt) | 1119105-13-3

• 英文名称: (η5-C5Me5Mo)2B5H7(μ3-OEt)
• CAS: 1119105-13-3
• 化学式: C₂₂H₄₂B₅Mo₂O
• 分子量: 568.51
• InChiKey: IXSFMIXQAIASLG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetrachloro(pentamethylcyclopentadienyl)molybdenum(V) 、 borane tetrahydrofuran 、 lithium (tetrahydrofuran)tetrahydroborate 以 甲苯 为溶剂， 以5%的产率得到(η5-C5Me5Mo)2B5H7(μ3-OEt)
  参考文献：
  名称：

  Unusual Open Eight-Vertex Oxamolybdaboranes: Structural Characterizations of (η⁵-C₅Me₅Mo)₂B₅(μ₃-OEt)H₆R (R = H and n-BuO)

  摘要：

  Reaction of (eta(5)-C5Me5)MoCl4 with a 10-fold excess of LiBH4 followed by thermolysis with excess BH3 center dot THF in toluene led to the formation of two oxamolybdaborane clusters, (eta(5)-C5Me5Mo)(2)B-5(mu(3)-OEt)H6R (2, R = H; 3, R = n-BuO). Clusters 2 and 3 have been characterized by H-1, B-11, and C-13 NMR spectra and X-ray crystal structure determinations. 2 and 3 are notable examples of oxametallaborane compounds where oxygen is contiguously bound to both the cluster metal (molybdenum) and the boron atom.

  DOI：

  10.1021/om801065r