pentacarbonyl(fluoromethyl isocyanide)chromium | 145957-73-9

• 英文名称: pentacarbonyl(fluoromethyl isocyanide)chromium
• CAS: 145957-73-9
• 化学式: C₇H₂CrFNO₅
• 分子量: 251.091
• InChiKey: LSPPLTOXTYUAMC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  pentacarbonyl(dichlorofluoromethylisocyanide)chromium 、 三正丁基氢锡 以 正己烷 为溶剂， 以82%的产率得到pentacarbonyl(fluoromethyl isocyanide)chromium
  参考文献：
  名称：

  Pentacarbonylchromium complexes containing the fluorinated isocyanide ligands H2FCNC and HF2CNC

  摘要：

  Pentacarbonyl(fluoromethyl isocyanide)chromium and pentacarbonyl(difluoromethyl isocyanide)chromium have been prepared. The vibrational spectroscopic data for the compounds indicate that these isocyanide ligands have a lower pi-acceptor/sigma-donor ratio than trifluoromethyl isocyanide.

  DOI：

  10.1016/0022-328x(92)85046-y