[2,6,7-trioxa-3,5,8-tris(trichloromethyl)-1,4-diphosphabicyclo[2.2.2]octane]PdCl2(NCC6H5) | 551945-27-8

• 英文名称: [2,6,7-trioxa-3,5,8-tris(trichloromethyl)-1,4-diphosphabicyclo[2.2.2]octane]PdCl2(NCC6H5)
• CAS: 551945-27-8
• 化学式: C₁₃H₈Cl₁₁NO₃P₂Pd
• 分子量: 784.562
• InChiKey: YKLNIKXQXSGRFL-XONLNLHLSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 [2,6,7-trioxa-3,5,8-tris(trichloromethyl)-1,4-diphosphabicyclo[2.2.2]octane]PdCl2(NCC6H5) 以 四氢呋喃 、 乙醚 为溶剂， 以75%的产率得到[2,6,7-trioxa-3,5,8-tris(trichloromethyl)-1,4-diphosphabicyclo[2.2.2]octane]PdCl2(tetrahydrofuran)
  参考文献：
  名称：

  Synthesis and X-ray structure of palladium dichloride complexed with THF and 2,6,7-trioxa-3,5,8-tris(trichloromethyl)-1,4-diphosphabicyclo[2.2.2]octane

  摘要：

  Palladium(II) dichloride containing both THF and the title bicyclic diphosphorus ligand 2 {i.e. P[OCH(CCl3)](3)P} has been synthesized and characterized by spectroscopic methods including X-ray crystallography. This compound is the first example of a metal complex containing the novel ligand 2. The X-ray structure of the complex reveals a virtually square-planar geometry around the palladium with trans oriented chlorine atoms and with 2 ligated by the PO3 terminus. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02192-7
• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 2,6,7-tris(trichloromethyl)-1,4-diphospha-3,5,8-trioxabicyclo<2,2,2>octane 以 甲苯 为溶剂， 以86%的产率得到[2,6,7-trioxa-3,5,8-tris(trichloromethyl)-1,4-diphosphabicyclo[2.2.2]octane]PdCl2(NCC6H5)
  参考文献：
  名称：

  Synthesis and X-ray structure of palladium dichloride complexed with THF and 2,6,7-trioxa-3,5,8-tris(trichloromethyl)-1,4-diphosphabicyclo[2.2.2]octane

  摘要：

  Palladium(II) dichloride containing both THF and the title bicyclic diphosphorus ligand 2 {i.e. P[OCH(CCl3)](3)P} has been synthesized and characterized by spectroscopic methods including X-ray crystallography. This compound is the first example of a metal complex containing the novel ligand 2. The X-ray structure of the complex reveals a virtually square-planar geometry around the palladium with trans oriented chlorine atoms and with 2 ligated by the PO3 terminus. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02192-7