1,4-bis(SnCl3 tricarbonyl tungsten cyclopentadienyl)-1,4-butadione | 342573-34-6

• 英文名称: 1,4-bis(SnCl3 tricarbonyl tungsten cyclopentadienyl)-1,4-butadione
• CAS: 342573-34-6
• 化学式: C₂₀H₁₂Cl₆O₈Sn₂W₂
• 分子量: 1198.15
• InChiKey: GQCQHPGDPOMGCA-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  盐酸 、 1,4-bis((C6H5)3Sn tricarbonyl tungsten cyclopentadienyl)-1,4-butadione*3H2O 以 二氯甲烷 为溶剂， 以90%的产率得到1,4-bis(SnCl3 tricarbonyl tungsten cyclopentadienyl)-1,4-butadione
  参考文献：
  名称：

  Bridging cyclopentadienyl MSn(IV) bonded polymetallic complexes: X-ray crystal structures of [(Me2SnCl)(CO)3MoC5H4C(O)CH2]2·CH2Cl2 and [(Ph3Sn)(CO)3WC5H4C(O)CH2]2·3H2O

  摘要：

  The dianions [(CO)(3)MC5H4C(O)CH2](2)(2-) reacted with RnSnX4-n in a 1:2 or 1:1 ratio to give tetranuclear complexes [(RnSnX3-n)(CO)(3)MC5H4C(O)CH2](2) (M = Mo or W; R = Ph or Me; X = Cl or Pr; n = 2 or 3), which have been characterized by elemental analysis, H-1 NMR and IR spectroscopy. The electron-withdrawing groups on the cyclopentadienyl rings greatly decrease the nucleophilicity of the metallic anions. Thus, only one halogen atom on tin was replaced by the metallic anion when the dianions reacted with SnR2X2. The crystal structures of complexes 4 (M = Mo; R = Me; X = Cl; n = 2) and 5 (M = W; R = Ph; n = 3) were determined by X-ray crystallography, indicating that both Mo and W atoms adopt a 3:4 piano stool structure, and the Sn-M bond length is 2.7755(3) Angstrom in complex 4 (Sn-Mo) and 2.8154(7) Angstrom in complex 5 (Sn-W). (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00647-1