Ni(1,4-bis(dicyclohexylphosphino)butane)CO2 | 141974-68-7

• 英文名称: Ni(1,4-bis(dicyclohexylphosphino)butane)CO2
• CAS: 141974-68-7
• 化学式: C₂₉H₅₂NiO₂P₂
• 分子量: 553.368
• InChiKey: DUDHZXZVVFMRBN-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Ni(1,4-bis(dicyclohexylphosphino)butane)CO2 在 氧气 作用下， 以 neat (no solvent) 为溶剂， 生成 (peroxocarbonato)1,4-bis(dicyclohexylphosphino)butanenickel(II)
  参考文献：
  名称：

  Carbon dioxide-transition metal complexes. IV. New Ni(0)CO2 complexes with chelating diphosphines: influence of PNiP angle on complex stabilities

  摘要：

  The reaction between Ni(O) complexes (dp) (dp = 1,2-bis(dicyclohexylphosphino)ethane, 1,3-bis(dicyclohexylphosphino) propane, 1,4-bis(dicyclohexylphosphino)butane; dcpe, dcpp, dcpb, respectively) and carbon dioxide is described. The influence of the P-Ni-P bond angle on the stability of the corresponding adducts is discussed. The reactions of Ni(dcpp)CO2 and Ni(dcpb)CO2 with dioxygen are also described.

  DOI：

  10.1016/s0020-1693(00)80758-6
• 作为产物：
  描述：

  1,4-bis(dicyclohexylphosphino)butanenickel(0) 在 二氧化碳 作用下， 以 甲苯 为溶剂， 生成 Ni(1,4-bis(dicyclohexylphosphino)butane)CO2
  参考文献：
  名称：

  Carbon dioxide-transition metal complexes. IV. New Ni(0)CO2 complexes with chelating diphosphines: influence of PNiP angle on complex stabilities

  摘要：

  The reaction between Ni(O) complexes (dp) (dp = 1,2-bis(dicyclohexylphosphino)ethane, 1,3-bis(dicyclohexylphosphino) propane, 1,4-bis(dicyclohexylphosphino)butane; dcpe, dcpp, dcpb, respectively) and carbon dioxide is described. The influence of the P-Ni-P bond angle on the stability of the corresponding adducts is discussed. The reactions of Ni(dcpp)CO2 and Ni(dcpb)CO2 with dioxygen are also described.

  DOI：

  10.1016/s0020-1693(00)80758-6