bis([7,7'-pyridine-2,6-diylbis(2,6-diazahept-1-en-1-yl)di-2-pyrrolato]bis(thiocyanato)dicopper(II)) | 168564-34-9

• 英文名称: bis([7,7'-pyridine-2,6-diylbis(2,6-diazahept-1-en-1-yl)di-2-pyrrolato]bis(thiocyanato)dicopper(II))
• CAS: 168564-34-9
• 化学式: C₅₀H₅₈Cu₄N₁₈S₄
• 分子量: 1293.58
• InChiKey: ODLBRMCJYNANSS-IEPFARNQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-吡咯甲醛 、 sodium thiocyanide 、 copper(II) acetate monohydrate 、 2,6-bis[N-(3-aminopropyl)aminomethyl]pyridine 以 甲醇 为溶剂， 以72%的产率得到bis([7,7'-pyridine-2,6-diylbis(2,6-diazahept-1-en-1-yl)di-2-pyrrolato]bis(thiocyanato)dicopper(II))
  参考文献：
  名称：

  Synthesis and Structure of a Tetracopper(II) Complex of a Pyrrole-Containing Unsymmetrical Binucleating Ligand: [Cu2L(NCS)2]2

  摘要：

  The unsymmetrical binucleating ligand H(2)L (L = C23H29N7) was formed in situ from the condensation of two equivalents of 2-pyrrolecarboxaldehyde with one equivalent of 2,6-bis[N-(3-aminopropyl)aminomethyl]-pyridine. Subsequent addition of two equivalents of copper acetate followed by two equivalents of sodium thiocyanate yielded [Cu(2)L(NCS)(2)](2), bis{[7,7'-pyridine-2,6-diylbis(2,6-diazahept-1-en-1-yl)di-2-pyrrolaro]bis(thiocyanato)dicopper(II)}. The complex exists as a dimer of dicopper(II) units held together by two 1,3-thiocyanate ion bridges.

  DOI：

  10.1107/s0108270195001363